Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (7): 681.

• Articles • Previous Articles     Next Articles

Syntheses and Characterization of Imidazolate Bridged Heteropolynuclear Complexes Containing Zn

Chen Dong, Tang Wenxia, Dai Anbang   

  1. Coordination Chemistry Institute, Nanjing Umversitg, Nanjing
  • Received:1988-10-11 Online:1990-07-24 Published:1990-07-24

Abstract: Five species of imidazolate bridged heteropolynuclear complexes containing Zn ( Ⅱ ) were prepared. In the syntheses, the kinetically inert, low spin d6 complexes, [(NH3)5CoIm]2+, [(NH3)5RhIm]2+ and [(en)2Co(Im)2]+ were used as ligands to react with mononuclear Zn ( Ⅱ ) complexes. By elemental analysis, molar conductivity, TGA, DSC and 1H NMR study, all bridged heteropolynuclear complexes were characterized.

Key words: Imidazolate bridged heteropolynuclear complexes, Zinc, Synthesis

TrendMD: