Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (8): 800.

• Articles • Previous Articles     Next Articles

Physico-Chemical Characterization of ZSM-5 Zeolite Synthesized Without Template

Guo Zhenya, Wang Jingzhong, Wang Kaixuan, Zhou Daming, Xiang Shouhe, Li Hexuan   

  1. Department of Chemistry and Department of Physics, Nankai University, Tianjm
  • Received:1988-11-15 Online:1990-08-24 Published:1990-08-24

Abstract: High resolution 29Si, 27Al, 23Na NMR is used to characterize the local structure of ZSM-5 zeolites with various Si/Al ratios synthesized without template. The dealumination from the framework of ZSM-5 zeolites treated at different temperatures and steaming times is studied by 29Si and 27Al MAS NMR. Asystematic X. R. D. study on the conditions under which the crystallographic shape of ZSM-5 type changes from orthorhombic to monoclinic(or vice versa) is reported.

Key words: Synthesis without template, Local structure, Dealumination, MAS NMR

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