Thermal Reduation Preparation of Co2+/Dy3+ Doped Cubic Fe3O4 and Their Magnetic Targeting Retention†

doi:10.7503/cjcu20170132

Abstract

Abstract:

Co²⁺/Dy³⁺ doped Fe₃O₄ nanoparticles(M_xFe_3-_xO₄) were synthesized by the thermal reduction and co-precipitation methods . The structure, morphology and magnetic properties of M_xFe_3-_xO₄ were characterized by means of X-ray diffractometer(XRD), transmission electron microscope(TEM) and vibrating sample magnetometer(VSM). The results show that the dopants did not change the maternal symmetry, and the maternal morphology gradually transformed from cube to sphere. The M_xFe_3-_xO₄ cubic magnetic particles have maximum saturation magnetization of 76.65 and 70.21 A·m²·kg^-1, respectively, when Co²⁺ actual doping amount is equal to 0.44 and Dy³⁺ actual doping amount is equal to 0.05. Compared with the superparamagnetic Fe₃O₄, the cubic high magnetic doped Fe₃O₄ nanoparticles showed a high retention rate in the simulated magnetic fluid magnetic targeting experiment in vitro.

Key words: Cubic Fe₃O₄, Doping, Magnetic property, Magnetic targeting in vitro, Lattice constant

CLC Number:

O613

TrendMD:

YANG Yuxiang, LIU Yicheng, ZHAO Min, YUAN Hongming, YAO Pingping, HUANG Yan, NI Chaoying. Thermal Reduation Preparation of Co²⁺/Dy³⁺ Doped Cubic Fe₃O₄ and Their Magnetic Targeting Retention^†[J]. Chem. J. Chinese Universities, 2017, 38(10): 1709.

Figures/Tables 13

References 34

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(hkl)	d_theoretical/nm	d_measured/nm	I/I₀
(111)	0.48399	0.48439	8.9606
(220)	0.29638	0.29700	35.1254
(311)	0.25276	0.25355	100
(222)	0.24200	0.24212	11.8279
(400)	0.20958	0.20869	17.9211
(422)	0.17112	0.17037	12.1864
(511)	0.16113	0.16016	25.8064
(440)	0.14819	0.14684	29.0322
(620)	0.13255	0.13209	4.6595
(622)	0.12638	0.12732	7.8853
(444)	0.12100	0.12123	4.6595

(hkl)	d_theoretical/nm	d_measured/nm	I/I₀
(111)	0.48399	0.48439	8.9606
(220)	0.29638	0.29700	35.1254
(311)	0.25276	0.25355	100
(222)	0.24200	0.24212	11.8279
(400)	0.20958	0.20869	17.9211
(422)	0.17112	0.17037	12.1864
(511)	0.16113	0.16016	25.8064
(440)	0.14819	0.14684	29.0322
(620)	0.13255	0.13209	4.6595
(622)	0.12638	0.12732	7.8853
(444)	0.12100	0.12123	4.6595

Co_xFe_3-_xO₄			Dy_xFe_3-_xO₄
x	a/nm	10⁵Relative error	x	a/nm	10⁵Relative error
0.06	0.8421	9.2211	0.05	0.8386	7.4738
0.14	0.8379	9.9783	0.13	0.8362	0.9782
0.29	0.8397	8.6385	0.28	0.8355	1.9035
0.44	0.8409	9.0054	0.43	0.8357	5.2441
0.58	0.8390	8.4927	0.53	2.498^*	0.1300

Co_xFe_3-_xO₄			Dy_xFe_3-_xO₄
x	a/nm	10⁵Relative error	x	a/nm	10⁵Relative error
0.06	0.8421	9.2211	0.05	0.8386	7.4738
0.14	0.8379	9.9783	0.13	0.8362	0.9782
0.29	0.8397	8.6385	0.28	0.8355	1.9035
0.44	0.8409	9.0054	0.43	0.8357	5.2441
0.58	0.8390	8.4927	0.53	2.498^*	0.1300

Co_xFe_3-_xO₄				Dy_xFe_3-_xO₄
x	M_s/(A·m²·kg^-1)	M_r/(A·m²·kg^-1)	H_c/(kA·m^-1)	x	M_s/(A·m²·kg^-1)	M_r/(A·m²·kg^-1)	H_c/(kA·m^-1)
0	66.36	20.26	183.9	0	66.36	20.26	183.9
0.06	68.99	30.76	307.8	0.05	70.21	17.13	147.8
0.14	71.50	47.71	663.4	0.13	65.62	14.73	105.7
0.29	75.08	49.74	897.5	0.28	52.25	13.22	132.2
0.44	76.65	42.57	1097.5	0.43	50.88	12.04	121.3
0.58	72.14	36.21	1746.2	0.53	47.28	9.61	113.4

Thermal Reduation Preparation of Co²⁺/Dy³⁺ Doped Cubic Fe₃O₄ and Their Magnetic Targeting Retention^†

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Figures/Tables 13

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Sample	Spacing/cm	Pulsed field voltage(V/Hz)	Magnetic peak/mT	Concentration after retention/(g·L^-1)	Retention rate(%)
Dy_0.05Fe_2.95O₄	2	500/2	269	0.0230	80.7
	2	600/2	290	0.0202	81.2
	2	700/2	350	0.0504	81.8
Co_0.44Fe_2.56O₄	2	500/2	249	0.0230	92.7
	2	600/2	271	0.0202	93.6
	2	700/2	346	0.0050	98.4
	10	500/2	55.5	0.1115	64.6
	10	600/2	79.2	0.1055	66.5
	10	700/2	96.3	0.1008	68.0
USPIO^[34]	2	500/2	279	0.0430	76.8
	2	600/2	378	0.0422	77.2
	2	700/2	433	0.0408	78.0
	10	500/2	53	0.0591	41.0

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