Microwave Synthesis and Electron Transfer Properties of a Series of New Porphyrin-anthraquinone Hybrids with Dipeptide Link and Their Metal Complexes

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (7): 1466.

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Microwave Synthesis and Electron Transfer Properties of a Series of New Porphyrin-anthraquinone Hybrids with Dipeptide Link and Their Metal Complexes

CHEN Nian-You^1*, ZHAO Sheng-Fang², DONG Jia-Qing³, TIAN You-Ping², LI Zao-Ying³

1. College of Chemical Engineering,
2. College of Chemistry and Life Science, Huanggang Normal University, Huanggang 438000, China;
3. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China

Received:2010-10-04 Revised:2011-03-16 Online:2011-07-10 Published:2011-06-02
Contact: CHEN Nian-You E-mail:chennyou@hgnu.edu.cn
Supported by:
湖北省自然科学基金面上项目(批准号: 2007ABA064)和湖北省教育厅重大项目(批准号: Z200727001)资助.

Abstract

Abstract: This paper reports the microwave synthesis of a novel porphyrin—anthraquinone hybrid with dipeptide link and its metal complexes. The new compounds have been confirmed by 1HNMR，IR，UV-Vis spectra and elementa1 analysis．The intramolecular electron transfer property （IETP）of these compounds was studied，the influence of the structure for IETP was discussed．

Key words: Porphyrin-anthraquinone, Dipeptide link, Metal porphyrin, Microwave synthesis, Intramolecular electron transfer

CLC Number:

O614

TrendMD:

CHEN Nian-You*, ZHAO Sheng-Fang, DONG Jia-Qing, TIAN You-Ping, LI Zao-Ying. Microwave Synthesis and Electron Transfer Properties of a Series of New Porphyrin-anthraquinone Hybrids with Dipeptide Link and Their Metal Complexes[J]. Chem. J. Chinese Universities, 2011, 32(7): 1466.

References

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Microwave Synthesis and Electron Transfer Properties of a Series of New Porphyrin-anthraquinone Hybrids with Dipeptide Link and Their Metal Complexes

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