Catalytic Conversion of 1-Methylnaphthalene as Tar Model Compound from Hot Coke Oven Gas over Ni/MgO/Al2O3 Catalysts

Abstract

Abstract: A series of Ni/MgO/Al₂O₃ catalysts were prepared by the method of co-impregnating boehmite(AlOOH) and characterized using N₂ adsorption and X-ray diffraction(XRD). 1-Methylnaphthalene was selected as a tar compound to investigate the performance of the Ni/MgO/Al₂O₃ catalysts for converting tar from hot coke oven gas(COG) with a low water to carbon molar ratio(n_H2O/n_C) into light fuel gases. The effects of MgO content and operating conditions were examined at 775 ℃ and n_H2O/n_C=0.7. The experimental results showed that the MgO modified Ni/MgO/Al₂O₃ catalysts possessed excellent catalytic activity and stability for the conversion of 1-methylnaphthalene to small gas molecules. TG analysis of the used catalysts showed that addition of MgO in the Ni/MgO/Al₂O₃ catalysts could significantly enhance resistance to carbon deposition. It was first found that the presence of higher concentration of H₂S(0.25%, volume fraction) could promote the conversion of tar to small gas molecules over the Ni/MgO/Al₂O₃ catalysts. This might be because the reversible adsorption of H₂S on the surface of metallic Ni led to the formation of ensemble of Ni sites more suitable for steam reforming and, meanwhile, inhibited dissolution and diffusion of carbon in metal Ni from dissociative adsorption of hydrocarbon, leading to the formation of coke disposition on the catalyst.

Key words: Ni catalyst, 1-Methylnaphthalene, Coke oven gas, Tar, Catalytic conversion

TrendMD:

YANG Jun , WANG Xue-Guang*, LI Lin, SHEN Kui, LU Xiong-Gang, DING Wei-Zhong*. Catalytic Conversion of 1-Methylnaphthalene as Tar Model Compound from Hot Coke Oven Gas over Ni/MgO/Al₂O₃ Catalysts[J]. Chem. J. Chinese Universities, 2010, 31(9): 1841.

References

[1]Youn M. H., Seo J. G., Cho K. M., Park S., Park D. R., Jung J. C., Song I. K.. Int. J. Hydrogen Energy[J], 2008, 33(19): 5052—5059 [2]Rakass S., Oudghiri-Hassani H., Rowntree P., Abatzoglou N.. J. Power Sources[J], 2006, 158(1): 485—496 [3]Rostrup-Nielsen J. R.. Catal. Today[J], 1997, 37(3): 225—232 [4]Armor J. N.. Appl. Catal. A[J], 1999, 176(2): 159—176 [5]Seo J. G., Youn M. H., Park S., Chung J. S., Song I. K.. Int. J. Hydrogen Energy[J], 2009, 34(9): 3755—3763 [6]Joseck F., Wang M., Wu Y.. Int. J. Hydrogen Energy[J], 2008, 33(4): 1445—1456 [7]Jess A.. Fuel[J], 1996, 75(12): 1441—1448 [8]Guo J. Z., Hou Z. Y., Gao J., Zheng X. M.. Energy Fuels[J], 2008, 22(3): 1444—1448 [9]Zhang Y. W., Li Q., Shen P. J., Liu Y., Yang Z. B., Ding W. Z., Lu X. G.. Int. J. Hydrogen Energy[J], 2008, 33(13): 3311—3319 [10]Yang Z. B., Zhang Y. Y., Wang X. G., Zhang Y. W., Lu X. G., Ding W. Z.. Energy Fuels[J], 2010, 24(2): 785—788 [11]Li L., Morishita K., Takarada T.. J. Chem. Eng. Jpn.[J], 2006, 39(4): 461—468 [12]Onozaki M., Watanabe K., Hashimoto T., Saegusa H., Katayama Y.. Fuel[J], 2006, 85(2): 143—149 [13]Mirua K., Kawase M., Nakagawa H., Ashida R., Nakai T., Ishikawa T.. J. Chem. Eng. Jpn.[J], 2003, 36(7): 735—741 [14]Jess A.. Chem. Eng. Process[J], 1996, 35(6): 487—494 [15]AI Xin-Peng(艾馨鹏), YUE Bao-Hua(岳宝华), WANG Xue-Guang(汪学广), YANG Jun(杨军), LU Xiong-Gang(鲁雄刚), DING Wei-Zhong(丁伟中). Acta Phys. Chim. Sin.(物理化学学报)[J], 2009, 25(8): 1517—1522 [16]YU Fei(于飞), YUE Bao-Hua(岳宝华), WANG Xue-Guang(汪学广), GENG Shu-Hua(耿淑华), LU Xiong-Gang(鲁雄刚), DING Wei-Zhong(丁伟中). Chin. J. Catal.(催化学报)[J], 2009, 30(7): 690—696 [17]Basagiannis A. C., Verykios X. E.. Appl. Catal. B[J], 2008, 82(1/2): 77—88 [18]XU Jun-Ke(徐军科), LI Zhao-Jing(李兆静), WANG Ji-Hui(汪吉辉), ZHOU Wei(周伟), MA Jian-Xin(马建新). Acta Phys. Chim. Sin.(物理化学学报)[J], 2009, 25(2): 253—260 [19]ZHANG Yue-Ping(张月萍), ZHU Xin-Li(祝新利), PAN Yun-Xiang(潘云翔), LIU Chang-Jun(刘昌俊). Chin. J. Catal.(催化学报)[J], 2008, 29(10): 1508—1066 [20]Hepola J., Simell P.. Appl. Catal. B[J], 1997, 14(3/4): 305—321 [21]Horiuchi T., Sakuma K., Fukui T., Kubo Y., Osaki T., Mori T.. Appl. Catal. A[J], 1996, 144(1/2): 111—120 [22]ZHANG Nuo-Wei(张诺伟), HUANG Chuan-Jing(黄传敬), KUANG Fei-Ping(匡飞平), GAO Xiao-Xiao(高晓晓), WENG Wei-Zheng(翁维正), WAN Hui-Lin(万惠霖). Acta Phys. Chim. Sin.(物理化学学报)[J], 2008, 24(12): 2165—2171 [23]LI Ji-Tao(李基涛), CHEN Ming-Dan(陈明旦), YAN Qian-Gu(严前古), WAN Hui-Lin(万惠霖), TSAI K. R. (蔡启瑞). Chem. J. Chinese Universities(高等学校化学学报)[J], 2000, 21(9): 1445—1447 [24]Engelen K., Zhang Y., Draelants D. J., Baron G. V.. Chem. Eng. Sci.[J], 2003, 58(3—6): 665—670 [25]Li D. L., Atake I., Shishido T., Oumi Y., Sano T., Takehira K.. J. Catal.[J], 2007, 250(2): 299—312 [26]Koo K. Y., Roh H. S., Seo Y. T., Seo D. J.,Yoon W. L., Park S. B.. Appl. Catal. A[J], 2008, 340(2): 183—190 [27]Corthals S., Nederkassel J. V., Geboers J., De Winne H., Van Noyen J., Moens B., Sels B., Jacobs P.. Catal. Today[J], 2008, 138(1/2): 28—32 [28]QIU Ye-Jun(邱业君), CHEN Ji-Xiang(陈吉祥), ZHANG Ji-Yan(张继炎). J. Fuel Chem. Technol.(燃料化学学报)[J], 2006, 34(4): 450—455 [29]Li C. S., Hirabayashi D., Suzuki K.. Fuel process Technol.[J], 2009, 90(6): 790—796 [30]Aparicio L. M.. J. Catal.[J], 1997, 165(2): 262—274 [31]Trimm D. L.. Catal. Today[J], 1999, 49(13): 3—10

Catalytic Conversion of 1-Methylnaphthalene as Tar Model Compound from Hot Coke Oven Gas over Ni/MgO/Al₂O₃ Catalysts

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