Synthesis and Characterization of SAPO-34-H(Hierarchical)

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (9): 1693.

• Articles • Previous Articles Next Articles

Synthesis and Characterization of SAPO-34-H(Hierarchical)

CHEN Lu¹, WANG Run-Wei^1*, DING Shuang¹, LIU Bing-Bing¹, XIA Hong², ZHANG Zong-Tao¹, QIU Shi-Lun^1*

1. State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130012, China;
2. Changchun Department for Product Quality Supervision and Testing, Changchun 130061, China

Received:2010-04-15 Online:2010-09-10 Published:2010-09-10
Contact: WANG Run-Wei. E-mail: rwwang@mail.jlu.edu.cn; QIU Shi-Lun. E-mail: sqiu@mail.jlu.edu.cn
Supported by:
国家自然科学基金(批准号: 20741001)、吉林省科技厅项目(批准号: 20090586)和石油化工催化材料与反应工程国家重点实验室（中国石油化工股份有限公司石油化工科学研究院）开放基金课题资助.

Abstract

Abstract: Silicoaluminophosphate zeolite SAPO-34 exhibits excellent performance in adsorption and catalysis due to its unique structure and small diameter. Mesoporous SAPO-34(named as SAPO-34-H) was prepared using a long\|chained organosilane as the only source of silicon and the mesoscale template. SAPO-34-H was characterized by various techniques. N₂ adsorption and TEM images results show that mesopores with a diameter of ca. 5.1 nm exist in the microporous crystals. NH₃-TPD results show that the introduction of mesopores results in the decrease of acidity.

Key words: Hierarchical porous material(SAPO-34-H), Micropore, Mesopore

TrendMD:

CHEN Lu, WANG Run-Wei*, DING Shuang, LIU Bing-Bing, XIA Hong, .... Synthesis and Characterization of SAPO-34-H(Hierarchical)[J]. Chem. J. Chinese Universities, 2010, 31(9): 1693.

References

[1]Tao Y., Kanoh H., Abrams L., Kaneko K.. Chem. Rev.[J], 2006, 106: 896—910 [2]Egeblad K., Christensen C. H., Kustova M.. Chem. Mater.[J], 2008, 20: 946—960 [3]Pérez-Ramírez J., Christensen C. H., Egeblad K., Groen J. C.. Chem. Soc. Rev.[J], 2008, 37: 2530—2542 [4]Meng X., Nawaz F., Xiao F. S.. Nano Today[J], 2009, 4: 292—301 [5]Jacobsen C. J. H., Madsen C., Houzvicka J., Schmidt I., Carlsson A.. J. Am. Chem. Soc.[J], 2000, 122: 7116—7117 [6]Schmidt I., Boisen A., Gustavsson E., Sthl K., Pehrson S., Dahl S., Carlsson A., Jacobsen C. J. H.. Chem. Mater.[J], 2001, 13: 4416—4418 [7]Tao Y., Kanoh H., Kaneko K.. J. Am. Chem. Soc.[J], 2003, 125: 6044—6045 [8]Xiao F. S., Wang L., Yin C., Lin K., Di Y., Li J., Xu R., Su D., Schlgl R., Yokoi T., Tatsumi T.. Angew. Chem. Int. Ed.[J], 2006, 45: 3090—3093 [9]Wang H., Pinnavaia T. J.. Angew. Chem. Int. Ed.[J], 2006, 45: 7603—7606 [10]Zhu H., Liu Z., Wang Y., Kong D., Yuan X., Xue Z.. Chem. Mater.[J], 2008, 20: 1134—1139 [11]Choi M., Cho H. S., Srivastava R., Venkatesan C., Choi D. H., Ryoo R.. Nature Mater.[J], 2006, 5: 718—723 [12]Choi M., Srivastava R., Ryoo R.. Chem. Commun.[J], 2006: 4380—4382 [13]Anderson M. W., Sulikowski B., Barrie P. J., Klinowski J.. J. Phys. Chem.[J], 1990, 94: 2730—2734 [14]Parakash A. M. , Unnikrishnan S.. J. Chem. Soc. Faraday Trans.[J], 1994, 90(15): 2291—2296 [15]Wu X. C., Abraha M. G., Anthony R. G.. Appl. Catal. A[J], 2004, 260: 63—69 [16]Stöcker M.. Micropor. Mesopor. Mater.[J], 1999, 29: 3—48 [17]Zhu J., Cui Y., Wang Y., Wei F.. Chem. Commun.[J], 2009: 3282—3284 [18]Liu G. Y., Tian P., Li J. Z., Zhang D. Z., Zhou F., Liu Z. M.. Micropor. Mesopor. Mater.[J], 2008, 111: 143—149 [19]Popova M., Minchev C., Kanazirev V.. Applied Catalysis A: General[J], 1998, 169: 227—235 [20]Pastore H. O., Coluccia S., Marchese L.. Annu. Rev. Mater. Res.[J], 2005. 35: 351—395

Synthesis and Characterization of SAPO-34-H(Hierarchical)

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	SHE Peihong, XU Wenzhou, GUAN Buyuan. Synthesis and Application of Silica/carbon-based Large-pore Mesoporous Nanomaterials [J]. Chem. J. Chinese Universities, 2021, 42(3): 671.
[2]	WEI Junyi, GAO Zhihua, HUANG Wei, AI Peipei, YAN Feifei, YOU Xiangxuan. Effect of Structural Ordering on the Performance of Mesoporous Carbon Supported CuCoCe Catalyst in the Synthesis of Higher Alcohols from Syngas^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1741.
[3]	NI Jie, WEI Hengyong, BU Jinglong, LIU Huixing, CUI Yi, LÜ Dongfeng, WEI Yingna, ZHANG Lifang. Synthesis of Ordered Mesoporous TiN Powder via Ammonia Reduction Nitridation Reaction and Its Electrochemical Performance^† [J]. Chem. J. Chinese Universities, 2017, 38(3): 355.
[4]	WANG Wei, XU Jiali, LIN Yuanfei, LI Xueyu, MENG Lingpu, LI Liangbin. Effect of Hot Stretching on the Structure of Polypropylene Microporous Membranes with in situ Small Angle X-Ray Scattering^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 2128.
[5]	ZHAO Li, YU Dongni, DAI Weili, WU Guangjun, LI Landong, GUAN Naijia. Catalytic Performance of Micro-/micro-mesoporous H-ZSM-5 Zeolites for Alkylation of Toluene with Methanol^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1834.
[6]	MOU Li*, QU Xue-Jian, WANG Chun-Yan. Synthesis and Catalytic Properties of Ordered Mesoporous Phenol-Formaldehyde Resins as Solid Acid Catalysts [J]. Chem. J. Chinese Universities, 2010, 31(8): 1643.
[7]	SHAO Yan-Qiu, WANG Hong-Su, GUAN Jing-Qi, YU Xiao-Fang, LIU Heng, KAN Qiu-Bin*. Synthesis and Characterization of New Organic-inorganic Based Catalyst——Effect of Steric Hindrance on Catalytic Performance [J]. Chem. J. Chinese Universities, 2010, 31(3): 592.
[8]	ZOU Yong-Cun, LU Feng-Guo, LI Guo-Dong*. Synthesis and DNA Adsorption Properties of Hierarchically Macro-mesoporous Titania Films [J]. Chem. J. Chinese Universities, 2010, 31(1): 30.
[9]	YANG Jian^1,2, WANG Xiao-Lin^2, TIAN Feng¹, LIN Ya-Kai², WANG Zheng¹. Diluent Selection of PVDF Membrane Prepared via* Thermally Induced Phase Separation [J]. Chem. J. Chinese Universities, 2008, 29(9): 1895.
[10]	WANG Hong-Su¹, WU Shu-Jie¹, SHAO Yan-Qiu^1,2, XU Ling¹, SONG Ke¹, XU Hai-Yan¹, KAN Qiu-Bin¹*. Synthesis and Characterization of a New Organic-inorganic Hybrid Mesoporous Basic Catalyst [J]. Chem. J. Chinese Universities, 2007, 28(8): 1528.
[11]	JIANG Yan-Qiu, LIU Yan-Hua, ZHAO Xu, ZHAO Jing-Zhe, TIAN Yu-Mei, WANG Zi-Chen. Preparation of Hollow Spheres of Si/Al Composite Oxide with Mesopores in the Shell Wall [J]. Chem. J. Chinese Universities, 2005, 26(6): 1018.
[12]	QIN Sheng, CHEN Liu-Sheng, SHI Yi, LIAO Qi, JIN Xi-Gao. Fabrication of Microporous Thin Films from Polyelectrolyte Multilayer Films [J]. Chem. J. Chinese Universities, 2005, 26(6): 1183.
[13]	CAI Zeng-Xuan, FANG Qun, CHEN Heng-Wu, FANG Zhao-Lun. Microfluidic Chip Systems Based on Membrane Liquid-liquid Extraction [J]. Chem. J. Chinese Universities, 2004, 25(S1): 149.
[14]	LIU Ying-Chun, WANG Qi, LU Ling-Hong. Studies on Diffusion Behavior of Simple Fluid in Micropores by Molecular Dynamics Simulation [J]. Chem. J. Chinese Universities, 2004, 25(5): 900.
[15]	ZHOU Qun, SUN Fang, CHUAI Bing-Jie, GU Jian-Sheng . Synthesis and Characterization of Zeolite FSM-16 and TiO₂/FSM-16 [J]. Chem. J. Chinese Universities, 2001, 22(8): 1400.