Highly-Ordered Hierarchical Composite Pore Materials Using Natural Plants as Templates

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (6): 1103.

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Highly-Ordered Hierarchical Composite Pore Materials Using Natural Plants as Templates

MA Jin-Yan¹, QU Feng-Yu^1,2*, XU Ying-Pu¹, LI Xiao-Feng¹

1. College of Chemistry and Chemical Engineering, Harbin Normal University,
2. Key Laboratory of Advanced Functional Materials and Excited State, Harbin 150025, China

Received:2009-10-20 Online:2010-06-10 Published:2010-06-10
Contact: QU Feng-Yu. E-mail: qufengyu@hrbnu.edu.cn
Supported by:
国家自然科学基金(批准号: 20871037)、黑龙江省自然科学基金(批准号: B2007-2)和黑龙江省教育厅科研项目(批准号: 11531229)资助.

Abstract

Abstract:

Two kinds of highly-ordered hierarchical pore materials with large poresize of 40—80 μm and mesoporous phase in inner-wall were synthesized successfully using two kinds of natural plants as macroporous templat, P123 as mesoporous templat. The hydrothermal stability of the samples was investigated in 37 ℃ water. Scanning electron microscopy(SEM), powder X-ray diffraction(XRD), high-resolution transmission electron microscopy(HRTEM) and N₂ adsorption/desorption are used to characterize the structure and properties of the products. The results confirmed that as-synthesized products own the macroporous and mesoporous phases. And the sample prepared with the stem of cattail as template shows good hydrothermal stability. This method can be used to replicate macroporous plant templates precisely. Since the aperture and pore structure of different plants are variable, it provides a natural condition for the synthesis of materials of different aperture holes and pore structure, and the organizational structure of the pore is to transport nutrient and water, so the hierarchical porous materials may have more superrior performance and application in the field of macromolecules separation, bone tissue regeneration ang drug delivery.

Key words: Bio-template; Highly ordered; Hierarchical composite pore; Hydrothermal stability

TrendMD:

MA Jin-Yan, QU Feng-Yu*, XU Ying-Pu, LI Xiao-Feng. Highly-Ordered Hierarchical Composite Pore Materials Using Natural Plants as Templates[J]. Chem. J. Chinese Universities, 2010, 31(6): 1103.

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Highly-Ordered Hierarchical Composite Pore Materials Using Natural Plants as Templates

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