Preparation, Characterization and Solution Properties of Poly(AM/DMC/C11AM)

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (11): 2308.

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Preparation, Characterization and Solution Properties of Poly(AM/DMC/C11AM)

AN Hui-Yong1,2,3, SONG Chun-Lei1, XU Kun1, LI Wen-Bo1, LIU Chang1, WANG Pi-Xin1*

1. Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry,Chinese Academy of Sciences, Changchun 130022, China;
2. Liaoning Shihua University, Fushun 113001, China;
3. Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Received:2010-01-05 Online:2010-11-10 Published:2010-11-10
Contact: WANG Pi-Xin. E-mail: pxwang@ciac.jl.cn
Supported by:
吉林省科技发展计划项目(批准号: 20096023)和吉林省与中国科学院科技合作资金项目(批准号: 2009SYHZ0027)资助.

Abstract

Abstract: A series of hydrophobically associating polyampholytes[poly(AM/DMC/C11AM)] was synthesized by the free radical polymerization in water. In this process, C11AM was synthesized by Ritter reaction, and used to copolymerize with acrylamide(AM) and [2-(methacryloyloxy)ethyl] trimethylammonium chloride. The structure of C11AM and poly(AM/DMC/C11AM) were confirmed by 1H NMR. Moreover, the rheology measurement and fluorescent characterization show that poly(AM/DMC/C11AM) possessed both of the hydrophobic association and antipolyelectrolyte behavior, which resulted in the super salt-resistance of the obtained polymers.

Key words: Anionic hydrophobic monomer, Hydrophobically associating polyampholyte, Hydrophobic association, Anti-polyelectrolyte behavior, Salt-resistance

TrendMD:

AN Hui-Yong, SONG Chun-Lei, XU Kun, LI Wen-Bo, LIU Chang, WANG Pi-Xin*. Preparation, Characterization and Solution Properties of Poly(AM/DMC/C11AM)[J]. Chem. J. Chinese Universities, 2010, 31(11): 2308.

References

[1]Volpert E., Selb J., Candau F.. Polymer[J], 1998, 39(5): 1025—1033 [2]Feng Y. J., Billon L., Grassl B., Bastiat G., Borisov O., Francois J.. Polymer[J], 2005, 46(22): 9283—9295 [3]Gao B. J., Jiang L. D., Kong D. L.. Colloid. Polym. Sci.[J], 2007, 285(8): 839—846 [4]GAO Bao-Jiao(高保娇), XU Ru-Xiu(许如秀), YU Shi-Kui(郁士奎), XU Li(徐立), GE Zhen(葛震). Chem. J. Chinese Universities(高等学校化学学报)[J], 2004, 25(6): 1164—1169 [5]Turner S. R., Siano D. B., Bock J.. Micellar Process for the Production of Acrylamide-alkyl Acrylamide Copolymers, US 4528348[P], 1985 [6]Lacik I., Selb J., Candau F.. Polymer[J], 1995, 36(16): 3197—3211 [7]McCormick C. L., Nonaka T., Johnson C. B.. Polymer[J], 1988, 29(4): 731—739 [8]Gao B. J., Jiang L. D., Liu K. K.. Eur. Polym. J.[J], 2007, 43(10): 4530—4540 [9]ZHANG Li-Ming(张黎明). Polym. Bull.(高分子通报)[J], 1998, 4(12): 80—85 [10]XUE Dong-Hua(薛冬桦), WANG Ji-Hua(王记华), SU Xue-Feng(苏雪峰), XU Kun(徐昆), WU Xiu-Li(吴修利), ZHANG Wen-De(张文德), WANG Pi-Xin(王丕新). Chem. J. Chinese Universities(高等学校化学学报)[J], 2008, 29(1): 212—216 [11]Fevola M. J., Bridges J. K., Kellum M. G., Hester R. D., McCormick. C. L.. J. Polym. Sci., Part A: Polym. Chem.[J], 2004, 42(13): 3236—3251 [12]Fevola M. J., Kellum M. G., Hester R. D., McCormick C. L.. J. Polym. Sci., Part A: Polym. Chem.[J], 2004, 42(13): 3252—3270 [13]Ezell R. G., McCormick C. L., Lokitz B., Treat N., McConaughy S. D., McCormick C. L.. J. Polym. Sci., Part A: Polym. Chem.[J], 2006, 44(15): 4479—4493 [14]Kujawa P., Rosiak J. K., Selb J., Candau F.. Macromol. Chem. Phys.[J], 2001, 202(8): 1384—1397 [15]Santos-Rosas R., Licea-Claverie A., Arndt K.. J. Mex. Chem. Soc.[J], 2006, 50(4): 164—174 [16]Yang Q. B., Chen Q., Tan Y., Zhang P. P., Wang P. X.. J. Polym. Sci., Part B: Polym. Phys.[J], 2008, 46(22): 2465—2474 [17]McCormick C. L., Hoyle C. E., Clark M. D.. Polymer[J], 1992, 33(2): 243—247 [18]Yeoh K. W., Chew C. H., Gan L. M., Koh L. L.. J. Macromol. Sci. Chem.[J], 1989, A26(4): 663—680 [19]ZHAO Dong-Bin(赵东滨), FENG Yu-Jun(冯玉军), LUO Ping-Ya(罗平亚). Oilfield Chemistry(油田化学)[J], 2000, 17(3): 260—262

Preparation, Characterization and Solution Properties of Poly(AM/DMC/C11AM)

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