Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (1): 177.

• Articles • Previous Articles     Next Articles

Synthesis of a Fullerene End-capped Poly(ε-caprolactone) by Fullerene Derivative Initiator

PENG Qi-Yun, KANG Feng, LI Juan, YANG Xin-Lin*   

  1. School of Life Science and Technology, Beijing Institute of Technology, Beijing 100081, China
  • Received:2009-04-27 Online:2010-01-10 Published:2010-01-10
  • Contact: YANG Xin-Lin. E-mail: xlyang@bit. edu. cn
  • Supported by:

    北京市自然科学基金(批准号: 2082020)与国家自然科学基金(批准号: 20672012)资助.

Abstract:

Using N-substituted 3,4-fullero pyrrolidine with an active hydroxyl group as an initiator, polymerization of ε-caprolactone was performed via ring-opening polymerization. The product was characterized by 1H NMR, 13C NMR and MALDI-TOF MS and its thermal properties were determined by TG and DSC. The results show that a fullerene end-capped poly(ε-caprolactone) is achieved, and the product is more thermally tolerative than poly(ε-caprolactone).

Key words: Fullerene end-capped poly(ε-caprolactone); ε-Caprolactone; Ming-opening polymerization

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