Syntheses and Characterizations of a Series of Transition Metal-substituted Aluminophosphates MAPO-CHA(M=Mn, Fe,Co, Zn)

Chem. J. Chinese Universities ›› 2009, Vol. 30 ›› Issue (12): 2349.

• Articles • Previous Articles Next Articles

Syntheses and Characterizations of a Series of Transition Metal-substituted Aluminophosphates MAPO-CHA(M=Mn, Fe,Co, Zn)

DING Hong, DUAN Fang-Zheng, CHEN Peng, LI Ji-Yang*

State Key Lab of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Received:2009-04-09 Online:2009-12-10 Published:2009-12-10
Contact: LI Ji-Yang. E-mail: lijiyang@jlu.edu.cn
Supported by:
国家自然科学基金(批准号: 20871051) 和吉林省科技发展计划项目(批准号:20080504)资助.

Abstract

Abstract:

Open-framework metal-substituted aluminophosphates have attracted more attentions owing to their interesting structural chemistry and potential applications in catalysis, ion exchange, magnetism, and photoluminescence. A series of metal-substituted aluminophosphates MAl(PO₄)₂[(C₂H₅)₂NH₂](denoted as MAPO-CHA, M=Mn, Fe, Co, Zn) was prepared under the hydrothermal conditions. Their frameworks are analogous to zeotype CHA structure in which 50% of the aluminum sites are replaced by transitional-metal ions. These compounds show photoluminescent properties, but the emission intensities are different due to the different transitional metals. Magnetic measurements reveal that there is very weak antiferromagnetic interaction among the metal centers of MAPO-CHA(M=Mn, Fe, Co). Crystal data of MnAPO-CHA: space group R3, a=1.4003(2) nm, c=1.5236(3) nm, V=2.5873(7) nm³, Z=9.

Key words: Aluminophosphate; Transition metal-substitution; CHA structure; Magnetism; Fluorescence

TrendMD:

DING Hong, DUAN Fang-Zheng, CHEN Peng, LI Ji-Yang* . Syntheses and Characterizations of a Series of Transition Metal-substituted Aluminophosphates MAPO-CHA(M=Mn, Fe,Co, Zn)[J]. Chem. J. Chinese Universities, 2009, 30(12): 2349.

References

[1]Wilson S. T., Lok B. M., Messina C. A., et al.. J. Am. Chem. Soc.[J], 1982, 104: 1146—1147
[2]Yu J., Xu R.. Acc. Chem. Res.[J], 2003, 36: 481—490
[3]Yu J., Xu R.. Chem. Soc. Rev.[J], 2006, 35: 593—604
[4]Bu X., Feng P., Stucky G. D.. Science[J], 1997, 278: 2080—2085
[5]Feng P., Bu X., Stucky G. D.. Nature[J], 1997, 388: 735—741
[6]Hartmann M., Kevan L.. Chem. Rev.[J], 1999, 99: 635—664
[7]SHI Lei(石磊), LI Ji-Yang(李激扬), DUAN Fang-Zheng(段芳正), et al.. Chem. J. Chinese Universities(高等学校化学学报)[J], 2005, 26(5): 819—821
[8]Thomas J. M., Raja R., Sankar G., et al.. Acc. Chem. Res.[J], 2001, 34: 191—200
[9]Song X., Li Y., Gan L., et al.. Angew. Chem. Int. Ed.[J], 2009, 48: 314—317
[10]Thomas J. M., Xu Y., Catlow C. R. R., et al.. Chem. Mater.[J], 1991, 3: 667—672
[11]Feng P. Y.. Chem. Commun.[J], 2001: 1668—1669
[12]Shi L., Li J., Yu J., et al.. Inorg. Chem.[J], 2003, 43: 2703—2707
[13]SMART and SAINT Software Packages[CP], Madison WI: Siemens Analytical X-ray Instruments Inc., 1996
[14]Sheldrick G. M.. Shelxl Program, Version 5.1[CP], Madison WI: Siemens Industrial Automation, Inc., 1997
[15]Brese N. E., O′Keefe M.. Acta Crystallogr.[J], 1991, B47: 192—197
[16]Ashtekar S., Chilukuri S. V. V., Prakash A. M., et al.. J. Phys. Chem.[J], 1996, 100: 3665—3670
[17]Tuel A., Arcon I., Tusar N. N., et al.. Micro. Mater.[J], 1996, 7: 271—284
[18]Rajic N., Gabrovsek R., Ristic A., et al.. Thermochimica Acta[J], 1997, 306: 31—36
[19]DUAN Fang-Zheng(段芳正), LI Ji-Yang(李激扬), DING Hong(丁红), et al.. Chin. J. Inorg. Chem.(无机化学学报)[J], 2008, 24(8): 1343—1346
[20]Yang M., Yu J., Di J., et al.. Inorg. Chem.[J], 2006, 45: 3588—3593
[21]Lin C., Yang Y., Chen C., et al.. Chem. Mater.[J], 2006: 2095—2101

Syntheses and Characterizations of a Series of Transition Metal-substituted Aluminophosphates MAPO-CHA(M=Mn, Fe,Co, Zn)

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 0

Recommended Articles

Metrics

Comments