Preparation and Swelling Behaviour of Polyampholyte Hydrogels Composed of Acryloyloxyethyl-trimethyl Ammonium Chloride and Acrylic Acid

Chem. J. Chinese Universities

• 研究论文 • Previous Articles

Preparation and Swelling Behaviour of Polyampholyte Hydrogels Composed of Acryloyloxyethyl-trimethyl Ammonium Chloride and Acrylic Acid

XUE Dong-Hua¹, WANG Ji-Hua¹, SU Xue-Feng², XU Kun², WU Xiu-Li¹, ZHANG Wen-De², WANG Pi-Xin²*

1. College of Biological Engineering, Changchun Univerestry of Technicology, Changchun 130012, China;
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2007-03-30 Revised:1900-01-01 Online:2008-01-10 Published:2008-01-10
Contact: WANG Pi-Xin

Abstract

Abstract: A series of poly(acryloyloxyethyl trimethyl ammonium choride-co-acrylic acid) hydrogels were synthesized by solution polymerization and the structure of hydrogel was characterized by FTIR and NMR. Meanwhile, the swelling behavior of hydrogels in distilled water with vairous pH values and the salt solutions with different concentrations were investigated. The results show that the hydrogel with equal molar negative charges and positive charges presented an antipolyelectrolyte effect. Ionic strength drastically affected the swelling behavior of hydrogels. At the same time, the swelling kinetic parameters of swelling process of hydrogels were also calculated in salt solutions with different concentrations and the results illuminated that the first 60% swelling process of hydrogels was governed by Fickian diffusion mechanism (n≤0.5) in the salt solution with a high ionic strength. With the increase of ionic strength, the swelling ratio of the hydrogels and diffusion coefficients increased.

Key words: Hydrogels, Amphiphile, Swelling, Ionic strength

CLC Number:

O631

TrendMD:

XUE Dong-Hua¹, WANG Ji-Hua¹, SU Xue-Feng², XU Kun², WU Xiu-Li¹, ZHANG Wen-De², WANG Pi-Xin²*. Preparation and Swelling Behaviour of Polyampholyte Hydrogels Composed of Acryloyloxyethyl-trimethyl Ammonium Chloride and Acrylic Acid[J]. Chem. J. Chinese Universities, doi: .

[1]	WANG Man, WANG Xin, ZHOU Jing, GAO Guohua. Efficient Synthesis of Dimethyl Carbonate via Transesterification of Methanol and Ethylene Carbonate Catalyzed by Poly（ionic liquid）s [J]. Chem. J. Chinese Universities, 2021, 42(12): 3701.
[2]	TIAN Yao,ZHANG Chunquan,WANG Wenzhe,ZHOU Yingfang,LU Yitong,ZHANG Peng,JIA Zhenfu,ZHOU Chengyu,CHEN Shilan. Preparation of Polyrotaxane Cross-linking Agent with “Pulley” Effect and Its Potential Application in Swelling Grain Used as Profile Control and Water Plugging Agent^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 2098.
[3]	YE Hui, LIU Yabo, JIA Yuxi. Numerical Simulation of Swelling and Drug Release Processes for Weak Polyelectrolyte Hydrogels^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 817.
[4]	YOU Aimei, CAO Yuhua, CAO Guangqun. Colloidal Magnetically Assembled Photonic Crystals and Ionic Strength Sensing^† [J]. Chem. J. Chinese Universities, 2017, 38(3): 479.
[5]	LIU Shirong, QIN Liyan, ZHANG Xiaodong, CHEN Mingqing. Highly Sensitive Colorimetric Sensing for Cu²⁺ by Inverse Opals of Photonic Crystal Hydrogels^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 1993.
[6]	GAO Tingting, LI Zhiying, GAO Ge, LIU Fengqi. Mechanical Strength and Swelling Behavior of Fatty Alcohol Polyoxyethylene Acrylate Hydrophobic Associated Hydrogels^† [J]. Chem. J. Chinese Universities, 2016, 37(9): 1744.
[7]	MA Ying, ZHANG Heng, YUAN Shiling. Hydration Structure of Partially Hydrolyzed Preformed Particle Gel^† [J]. Chem. J. Chinese Universities, 2015, 36(2): 386.
[8]	WANG Dan, BAI Yin-Juan, HE Gui-Qiang, ZHANG Yu-Cheng, GONG Yong-Kuan, ZHANG Shi-Ping. Synthesis, Characterization and Properties of a Novel Unsaturated Polyphosphoester [J]. Chem. J. Chinese Universities, 2013, 34(6): 1555.
[9]	KOU Ying-Ying, MENG Qing-Bin, LIU Ke-Liang. Coassembly of Palmitic Acid Modified α-Helical Peptide Amphiphiles [J]. Chem. J. Chinese Universities, 2012, 33(11): 2476.
[10]	YANG Xiao-Gang, LIU Li-Jian, LIAO Li-Qiong. Synthesis and Properties of Novel Polyglycerol Hydrogels Containing L-Lactic Acid Groups [J]. Chem. J. Chinese Universities, 2011, 32(4): 964.
[11]	LI Guang-Quan, YU Jing-Sheng, LI Guo-Wen*. Novel Fluorescent Vesicular Sensor for Saccharides Based on Boronic Acid\\|diol Interaction [J]. Chem. J. Chinese Universities, 2011, 32(3): 793.
[12]	TAN Guo-Xin*, WANG Ying-Jun, ZHANG Shu-Jiang, CHENG Rong, NING Cheng-Yun, LIU Xu-Jian. Adhesion and Proliferation of BMSCs on the Surface of PEGDA-based Hydrogel by Low-temperature Plasma [J]. Chem. J. Chinese Universities, 2011, 32(2): 402.
[13]	YUAN Fei, LI Qiu-Yue, WANG Wei*. Synthesis of Amphiphilic Block Codendrimers Gx-PBE-b-Gx-PMPA(OH)x2 and Study on Temperature Dependence of Multiple Hydrogen Bonds [J]. Chem. J. Chinese Universities, 2011, 32(11): 2667.
[14]	LI Jian-Jun, ZHANG Cheng-Liang, DING Shu-Jiang, QU Xiao-Zhong, YANG Zhen-Zhong*. Template Synthesis of Composite Hollow Spheres [J]. Chem. J. Chinese Universities, 2009, 30(9): 1904.
[15]	LI Guang-Quan, ZHANG Yu-Jian, ZHANG Xiao, HE Zhen-Feng, CHEN Yun-Xia,LI Guo-Wen*. Synthesis of a Novel Amphiphile Containing Both Phenylboronic Acid and Naphthalene and Preparation of the Fluorescent Vesicular Sensor [J]. Chem. J. Chinese Universities, 2009, 30(9): 1809.

Preparation and Swelling Behaviour of Polyampholyte Hydrogels Composed of Acryloyloxyethyl-trimethyl Ammonium Chloride and Acrylic Acid

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments