Chem. J. Chinese Universities

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Spatio-temporal Symmetry-breaking of Temperature Field and Temperature Wave in a Nonisothermal Single-Molecule Chemical Reaction System

HAN Yu-Min, LI Zhi, LUO Jiu-Li*   

  1. Institute of Chemical Physics, College of Chemistry, Sichuan University, Chengdu 610064, China
  • Received:2006-06-05 Revised:1900-01-01 Online:2007-04-10 Published:2007-04-10
  • Contact: LUO Jiu-Li

Abstract: Spatio-temporal symmetry-breaking of temperature field in a small spatially distributed Lindemann single-molecule chemical reaction-diffusion-heat conduction system is studied by both the linear stability analysis and the computer numerical simulation. It is shown that the temperature wave can appear beyond spatio-temporal symmetry-breaking bifurcation at a certain constraint controlled externally and a fixed boundary condition for the model system.

Key words: Chemical reaction-diffusion-heat conduction coupling, Lindemann single-molecule reaction model, Spatio-temporal symmetry-breaking of temperature field, Temperature wave

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