Chem. J. Chinese Universities ›› 2006, Vol. 27 ›› Issue (3): 410.
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GUO Xi-Ming1,SU Lian-Jiang2,YU Lian-Xiang1,SHI Tong-Shun1*
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Abstract:
The L-glutamicacyl dichloride was prepared by the reaction of L-glutamic acid(NH2 was protected by using acetyl group) with SOCl2,then reacted with 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin,to give L-glutamic acid bridged diporphyrins. The compound was confirmed by using IR,1H NMR,UV-Vis and elemental analysis. The chiral characteristics of the dimmer was studied by the circular dichroism(CD) spectrum.
Key words: L-Glutamic acid; 5-(4-Hydroxylphenyl)-10,15,20-triphenylporphyrin(MHTPP); Dimers; Circula dichroism spectrum
CLC Number:
O635.2
TrendMD:
GUO Xi-Ming, SU Lian-Jiang, YU Lian-Xiang, SHI Tong-Shun. Synthesis and Characterization of L-Glutamic Acid Bridged Porphyrin and Its CD Spectrum[J]. Chem. J. Chinese Universities, 2006, 27(3): 410.
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http://www.cjcu.jlu.edu.cn/EN/Y2006/V27/I3/410
