Synthesis and Fluorescence Property of BaLiF3∶Ce3+ Nanoparticles

Chem. J. Chinese Universities ›› 2006, Vol. 27 ›› Issue (2): 215.

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Synthesis and Fluorescence Property of BaLiF₃∶Ce³⁺ Nanoparticles

ZHU Guo-Xian ^1,2, LIAN Hong-Zhou², MO Feng-Shan ^1,2, SHI Chun-Shan²

1. School of Life Science and Chemistry, Zhanjiang Normal College, Zhanjiang 524048, China;
2. Key Laboratory of Rare Earth Chemistry and Physics, Chinese Academy of Sciences, Changchun 130022, China

Received:2005-04-14 Online:2006-02-10 Published:2006-02-10
Contact: SHI Chun-Shan,E-mail: cshi@ciac.jl.cn

Abstract

Abstract:

Abstract The complex fluoride BaLiF₃and BaLiF₃∶Ce³⁺ nanocrystals were synthesized in cetyltrimethylammonium bromide(CTAB)/2octanol/water microemulsion systems. XRD analysis shows that the products were single phase and XPS analysis shows the oxygen content was low. The result of ESEM confirms that the average size of the BaLiF₃ nanocrystals was 28 nm in diameter. The emission peak of the BaLiF₃∶Ce³⁺nano-particles synthesized by microemulsion shows obvious blue shift in comparison with that of BaLiF₃∶Ce³⁺synthesized by the reaction at a high temperature and full width at half maximum(FWHM) of emission band was broaden.

Key words: BaLiF₃∶Ce³⁺ ; Microemulsion; Nanoparticles; Fluorescence

CLC Number:

O612

TrendMD:

SHU Guo-Xian, Hong-Zhou, MO Feng-Shan, SHI Chun-Shan. Synthesis and Fluorescence Property of BaLiF₃∶Ce³⁺ Nanoparticles[J]. Chem. J. Chinese Universities, 2006, 27(2): 215.

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Synthesis and Fluorescence Property of BaLiF₃∶Ce³⁺ Nanoparticles

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