In situ Polymerization of Ammonium Ion Monomers Intercalated in the Montmorillonite Template

Chem. J. Chinese Universities

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In situ Polymerization of Ammonium Ion Monomers Intercalated in the Montmorillonite Template

FENG Li¹, YANG Mu², WANG Ge²

1. School of Science, Beijing University of Chemical Technology, Beijing 100029, China;
2. School of Material Science and Engineering, Beijing University of Science and Technology, Beijing 100083, China

Received:2006-02-24 Revised:1900-01-01 Online:2006-11-10 Published:2006-11-10

Abstract

Abstract: The protonated forms of four ammonium salts(dimethyl diallyl ammonium chloride, DMDAAC; trimethylallyl ammonium chloride, TMAAC; acryloxyethyl trimethylammonium chloride, DAC; 2-methyl acryloxyethyltrimethylammonium chloride, DMC) were introduced into the interlayer region of montmorillonite template through ion-exchange reaction. X-ray diffractometry and FTIR spectra displayed that all the four monomers were intercalated into the layer region
successfully, but only two monomers undertook in situ polymerization. The different reaction activities of the four monomers were attributed to the different
space arrangement and steric hindrance of the monomers in the interlayer of montmonrillonite template.

Key words: Montmorillonite, In situ intercalation polymerization, Ammonium ion monomer

CLC Number:

O631

TrendMD:

FENG Li¹, YANG Mu², WANG Ge²
. In situ Polymerization of Ammonium Ion Monomers Intercalated in the Montmorillonite Template[J]. Chem. J. Chinese Universities, doi: .

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In situ Polymerization of Ammonium Ion Monomers Intercalated in the Montmorillonite Template

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