Electrooxidation of Hydroxypivalaldehyde at  PbO2-SPE Composite Electrode

Abstract

Abstract:

The lead dioxide-solid polymer electrolyte(SPE) membrane composite electrode was prepared by hot-press and electroplating methods. The electrooxidation behavior of hydroxypivalaldehyde was studied by means of cyclic voltammetric and cell voltage-overpotential curves. The current response at the PbO₂-SPE composite electrode and cell voltage were analyzed with or without liquid supporting electrolyte in the anolytes as well as in different catholytes. It was found from the experiment restuts that the PbO₂-SPE composite electrode had a good electrocatalytic activity for the oxidation of hydroxypivalaldehyde.

Key words: PbO₂-SPE composite electrode; Solid polymer electrolyte; Hydroxypivalaldehyde; Electrooxidation

CLC Number:

O646

TrendMD:

YU Jian-Guo, CAO Xue-Jing, ZHANG Heng-Bin, LI Fei, XU Yu-Ling. Electrooxidation of Hydroxypivalaldehyde at PbO₂-SPE Composite Electrode[J]. Chem. J. Chinese Universities, 2006, 27(1): 121.

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Electrooxidation of Hydroxypivalaldehyde at PbO₂-SPE Composite Electrode

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