Reverse Atom Transfer Radical Polymerization of MMA Catalyzed by FeBr3/Me-6TREN

Abstract

Abstract: The reverse atom transfer polymerization of MMA catalyzed by FeBr₃/Me-6TREN was studied in this paper. The molecular weight increased with the increase of the conversion and was in a good agreement with the theoretical value. The molecular weight distribution of the resulted PMMA was very narrow(1.06). These results indicate that the polymerization was well-controlled. The effect of morlar ratio of catalyst to initiator and FeBr₃ to ligand Me-6TREN on the control of the polymerization were studied. In addition, the activation energy of polymerization of MMA was calculated to be 29.35 kJ/mol, which was a bit smaller than that of Cl^-mediated reverse ATRP.

Key words: Atom transfer radical polymerization(ATRP), FeBr₃, Tris(N,N-dimethylaminoethyl)amine(Me-6TREN)

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LI Zhong-Hui, ZHANG Yong-Ming, LIU Yan-Fei, XUE Min-Zhao, LIU Yan-Gang . Reverse Atom Transfer Radical Polymerization of MMA Catalyzed by FeBr₃/Me-6TREN[J]. Chem. J. Chinese Universities, 2005, 26(8): 1570.

References

[1] Matyjaszew sk i K.,Xia J..Chem.Rev.[J],2001,101:2921—2990 [2] Pan C.Y.,Tao L.,Liu Y..Ch inese Jou rnal of Po lym er Science[J],2002,20(4):353—360 [3] Feng X.S.,Pan C.Y..Macrom o lecu les[J],2002,35(6):2084—2089 [4] Shem p er B.S.,Acar A.E.,Math ias L.J..J.Po lym.Sc.i,Part A:Po lym.Chem.[J],2002,40:334—343 [5] Klok H.A.,Becker S.,Schuch F..Macrom o lecu lar Chem istry and Physics[J],2002,203(8):1106—1113 [6] Dum as P.,Delaite C.,Hu rtrez G..Macrom o lecu lar Sym po sia[J],2002,183:29—33 [7] Carlm ark A.,Vestberg R.,Jon sson E.M..Po lym er[J],2002,43(15):4237—4242 [8] Jiang B.B.,Yang Y.,Deng J.et al..Jou rnal of App lied Po lym er Science[J],2002,83(10):2114—2123 [9] Yan D.,Zhou Y.,Hou J..Science[J]2004,303(2):65—67 [10] He X.H.,Zhang H.L.,Wang X.Y..Po lym er Bu lletin[J],2002,48(4—5):337—344 [11] LiM.H.,Keller P.,Grelet E..Macrom o lecu lar Chem istry and Physics[J],2002,203(4):619—626 [12] Kasko A.M.,Grunw ald S.R.,Pugh C..Macrom o lecu les[J],2002,35(14):5466—5474 [13] Tian Y.Q.,Watanabe K.,Kong X.X..Macrom o lecu les[J],2002,35(9):3739—3747 [14] Kim J.B.,Huang W.X.,Bruen ing M.L.et al..Macrom o lecu les[J],2002,35(14):5410—5416 [15] Bai J.,Pang J.B..Ch inese Jou rnal of Po lym er Science[J],2002,20(3):261—267 [16] Mo ri H.,Seng D.C.,Zhang M.F..Langm u ir[J],2002,18(9):3682—3693 [17] Bo ttcher H.,Hallen sleben M.L.,Nu ss S..Jou rnal of Materials Chem istry[J],2002,12(5):1351—1354 [18] Farm er S.C.,Patten T.E..Chem istry of Materials[J],2001,13(11):3920—3926 [19] Ando T.,Kam igaito M.,Saw am o to M..Macrom o lecu les[J],1997,30:4507—4510 [20] Teodo rescu M.,Gayno r S.G.,Matyjaszew sk i K..Macrom o lecu les[J],2000,33:2335—2339 [21] Zhu S.,Yan D..Macrom o lecu les[J],2000,33:8233—8238 [22] Zhu S.,Yan,D.,Zhang G..J.Po lym.Sci.,Part A:Po lym.Chem.[J],2001,39:765—774 [23] Wo lfe P.S.,Nguyen S.T..J.Am.Chem.Soc.Po lym.Prep r.[J],1998,39:552—554 [24] Lou ie J.,Grubb s R.H..Chem.Comm un.[J],2000:1479—1483 [25] Ciam po lin iM.,Nard i N..Ino rg.Chem.[J],1966,5:41—44 [26] Xia J.,Gayno r S.G.,Matyjaszew sk i K..Macrom o lecu les[J],998,31:5958—5961 [27] Qiu J.,Gayno r,S..Matyjaszew sk i K..Macrom o lecu les[J],1999,32:2872—2875 [28] Gilbert R.G..Pu re App l.Chem.[J],1996,68:1491—1494 [29] Wang J.L.,Grim aud T.,Matyjaszew sk i K..Macrom o lecu les[J],1997,30:6507—6509 [30] Matyjaszew sk i K.,Patten,T.E.,Xia J..J.Am.Chem.Soc.[J],1997,119:674—678

Reverse Atom Transfer Radical Polymerization of MMA Catalyzed by FeBr₃/Me-6TREN

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