Synthesis of the Novel Inorganic-organic Hybrid Material with Polymer Metal Complex by Atom Transfer Radical Polymerization

Abstract

Abstract: The homopolymer brushes of polyacrylamide(PAAM) on spherical silicon gel were synthesized by atom transfer radical polymerization(ATRP). The silicon gel initiator was prepared by self-assemble. Utilizing these modified silicon gel as the substrate, a kind of novel inorganic-organic hybrid material with the polymer metal complex was synthesized. The result of ESR indicates that the inorganic/organic hybrid material with the polymer metal complex based on silicon gel possesses well paramagnetis.

Key words: Atom Transfer Radical Polymerization(ATRP), Polymer metal complex, Inorganic-organic hybrid material

CLC Number:

O631

TrendMD:

LI Hong-Tu, ZHANG Hong-Wen, XU Ya-Xin, ZHANG Kai, JIN Xu, ZHOU Xin, WANG Jing-Yuan. Synthesis of the Novel Inorganic-organic Hybrid Material with Polymer Metal Complex by Atom Transfer Radical Polymerization[J]. Chem. J. Chinese Universities, 2005, 26(7): 1381.

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Synthesis of the Novel Inorganic-organic Hybrid Material with Polymer Metal Complex by Atom Transfer Radical Polymerization

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