Synthesis, Crystal Structure and Electrochemical Properties of Two Novel Diferrocenyl Thiourea Derivatives FcL1 And FcL2

Abstract

Abstract: Two novel diferrocenyl thiourea derivatives FcL₁ and FcL₂ were synthesized. The structures of the compounds were determined by elemental analysis, IR and ¹H NMR spectra. The X-ray single crystal structure analysis of FcL₁ indicates that the crystal belongs to triclinic system, P1 space group, there was a hydrogen bond in the compound. It was found that the electrochemical property of FcL₁ was very similar with that of FcL₂, the redox couple(FcL₁: E_1/2=600 mV; FcL₂: E_1/2=605 mV) was corresponding to the progress of 2Fc³⁺+2e^-2Fc^²⁺, which can be rationalized by the equivalent environment of the ferrocene subunit in each case. The difference between m-ferrocenylaniline and p-ferrocenylaniline didn't cause the distinct change for their diffusion coefficient(D), but caused the distinct change for their electrochemical reaction rate constant(k_s).

Key words: Ferrocenyl thiourea derivatives, Synthesis, Crystal structure, Electrochemical property

CLC Number:

O627

TrendMD:

XU Yan, WANG Fei, FU Yong, ZHANG Qiao-Hong, YE Bao-Xian, SONG Mao-Ping, WU Yang-Jie. Synthesis, Crystal Structure and Electrochemical Properties of Two Novel Diferrocenyl Thiourea Derivatives FcL₁ And FcL₂[J]. Chem. J. Chinese Universities, 2005, 26(6): 1081.

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Synthesis, Crystal Structure and Electrochemical Properties of Two Novel Diferrocenyl Thiourea Derivatives FcL₁ And FcL₂

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