Tris(2,2'-bipyridyl) ruthenium(Ⅱ) Chemiluminescence Reaction and Its Apllication to a Microchip

Abstract

Abstract:

Tris(2,2'-bipyridy) ruthennium(Ⅱ)(Ru(bipy)₃²⁺) chemiluminescence(CL) reaction was investigated as a post separation detection scheme for microchip.The oxalic acid was selected as a sample to evaluate the established system.Under the optimum experimental conditions,the linear range and detection limit of oxalic acid were from 5×10^-6 to 1×10^-4 and 2.0×10^-6 mol/L,respectively.The novel microchip CL detection system could be used for the separation and determination of some organic acids and nucleic acids.

Key words: Microchip, Ru(bipy)₃²⁺, Chemiluminescence detection, Oxalic acid

TrendMD:

JI Xing-Hu, HE Zhi-Ke, PANG Dai-Wen, CHENG Jie-Ke. Tris(2,2'-bipyridyl) ruthenium(Ⅱ) Chemiluminescence Reaction and Its Apllication to a Microchip[J]. Chem. J. Chinese Universities, 2004, 25(S1): 80.

[1]	SONG Dewen, WANG Mingwang, WANG Yani, JIAO Zhenmei, NING Hui, WU Mingbo. Progress of CO₂ Electroreduction to Oxalic Acid [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220248.
[2]	XUE Hong-Hai, PENG Fei, ZHAO Xu-Hui, KANG Chun-Li*, LI Lin-Lin, LI Zhe, LIU Han-Fei. Photoconversion of p-Chlorphenol in Photo-Fe³⁺-oxalic Acid System in Ice [J]. Chem. J. Chinese Universities, 2011, 32(5): 1077.
[3]	XU Chun-Xiu, YIN Xue-Feng,*. Cellular Uptake of SiO₂ Particles Under Dynamic Conditions in a Microfluidic Chip [J]. Chem. J. Chinese Universities, 2010, 31(9): 1712.
[4]	LI Xin^1,2*, CHEN Cui-Xian², LI Ji-Ding². Effect of Oxalic Acid on Rheological Variation, Thermodynamic Variaton and Formation Kinetics in Asymmetric Membrane Formation [J]. Chem. J. Chinese Universities, 2009, 30(1): 203.
[5]	LIU Yan-Ming^*, TIAN Wei. Sensitive Determination of Drug Alkaloids by Capillary Electrophoresis with Electrochemiluminescence Detection and Its Applications to Analysis of Human Urine [J]. Chem. J. Chinese Universities, 2009, 30(1): 51.
[6]	LIU Yan-Ming*, CAO Jun-Tao, ZHENG Yan-Li. Sensitive Determination of Norepinephrine by Capillary Electrophoresis with Indirect Electrochemiluminescence Detection and Its Application to Analysis of Human Urine [J]. Chem. J. Chinese Universities, 2008, 29(1): 81.
[7]	LIU Yan-Ming^1*; MU Hai-Bei¹; WANG Cheng-Quan¹; CHEN Yong-Hong²; LI Fu-Rong³; WANG Jun-Hua⁴; CHENG Jie-Ke⁴. Highly Sensitive Chemiluminescence Detection of Tumor Marker alpha-Fetoprotein in Human Sera with Capillary Electrophoresis Immunoassay [J]. Chem. J. Chinese Universities, 2006, 27(7): 1242.
[8]	WANG Wei-Peng^1,2, NI Kun-Yi², ZHOU Guo-Hua^1,2. Simultaneous Detection of Multiplex SNPs by Adapter-ligation Mediated Allele-specific Amplification(ALM\\|ASA) on CE-chip Electrophoresis Device [J]. Chem. J. Chinese Universities, 2006, 27(10): 1856.
[9]	ZHOU Xiao-Mian, LI Da-Zhi, SHEN Zheng, LIU Wei, LI Gui-Ru, LIN Bing-Cheng. Interaction Between Domoic Acid and Double-Stranded Oligodeoxy-nucleotide Studied by Using Microchip-based Non-gel Sieving Electrophoresis [J]. Chem. J. Chinese Universities, 2005, 26(7): 1252.
[10]	FAN Jun, LIANG Heng, SHI Xiao-Qiang. Segment Threshold Wavelet Denosing of Chemiluminescence Signal from Micro-fluidic Electrophoresis Chip [J]. Chem. J. Chinese Universities, 2005, 26(11): 2010.
[11]	WU You-Yi, LIN Jin-Ming, CAI Zong-Wei. Microchip Capillary Electrophoresis(MCCE) with Column-end Amperometric Detection and Its Preliminary Applications [J]. Chem. J. Chinese Universities, 2004, 25(S1): 88.
[12]	YANG Xiu-Rong, QIU Hai-Bo, YAN Ji-Lin, ZHAO Xiao-Cui, WANG Er-Kang. Simultaneous Detection of Medicine Molecule via Microchip Capillary Electrophoresis Electrochemistry/Electro-chemiluminescence [J]. Chem. J. Chinese Universities, 2004, 25(S1): 99.
[13]	HE Feng-Yun, LIU Ai-Lin, XIA Xing-Hua. Poly(dimethylsiloxane) Microchip Capillary Electrophoresis with Electrochemical Detector for Fast Measurements of Acetaminophen and Its Hydrolysate [J]. Chem. J. Chinese Universities, 2004, 25(S1): 124.
[14]	LI Hai-Fang, LIN Jin-Ming, QU Feng. A Simple Microchip Electrophoresis System with Sequential Injection Sample Introduction and Integrated Laser Induced Fluorescence Detection [J]. Chem. J. Chinese Universities, 2004, 25(S1): 139.
[15]	LI Zheng-Ping, FAN Shuang-Shuang, ZHANG Li-Na, SHI Sheng-Xun. Time-resolved Chemiluminescence Method for Determination of Micro-proteins Based on their Complexation with Cu(Ⅱ) [J]. Chem. J. Chinese Universities, 2004, 25(S1): 161.

Tris(2,2'-bipyridyl) ruthenium(Ⅱ) Chemiluminescence Reaction and Its Apllication to a Microchip

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments