Synthesis of Amino-capped Aniline Pentamer and UV-Vis Spectral Study

Abstract

Abstract: Compound B was synthesized through oxidative coupling reaction of p-phenylene-diamine and compound A(acetylamino-capped aniline dimer). This synthetic route protected the N-phenyl-1,4-phenylenediamine from further reaction. The pentamer was synthesized by the hydrolysis of compound B(acetylamino-capped aniline pentamer) and was characterized by IR, elemental analysis and MALDI-TOF-MS. The chemical oxidation process of the pentamer was studied by UV-Vis spectra. It was found the pentamer was oxidized to its EB form and then to the pernigraniline oxidation state.

Key words: Oligoaniline, Amino-capped aniline pentamer, UV-Vis spectrum

CLC Number:

O631

TrendMD:

CHEN Liang, YU You-Hai, MAO Hua-Ping, LU Xiao-Feng, ZHANG Wan-Jin, WEI Yen . Synthesis of Amino-capped Aniline Pentamer and UV-Vis Spectral Study[J]. Chem. J. Chinese Universities, 2004, 25(9): 1768.

[1]	ZHOU Mingjuan, YAN Ying, CHAO Danming. Synthesis and Properties of Electrochromic/Electrofluorochromic Bifunctional Polymer^† [J]. Chem. J. Chinese Universities, 2019, 40(1): 147.
[2]	CHAO Dan-Ming, WANG Shu-Tao, CHI Mao-Qiang, YANG Rui, WANG Ce. Synthesis and Properties of Novel Poly(amic acid) Bearing Oligoaniline Pendants [J]. Chem. J. Chinese Universities, 2013, 34(7): 1753.
[3]	LI Yong-Ling, ZHANG Jian-Gang, WEI Yan-Li, CHENG Fang-Qin. Detection of Cysteine in Aqueous Solution Based on Indicator Displacement by Ultraviolet-Visible and Colorimetric Methods [J]. Chem. J. Chinese Universities, 2012, 33(06): 1158.
[4]	HE Li-Bing, BIAN Xiu-Jie, CHAO Dan-Ming, LI Zhi-Liang, LI Ye, WANG Ce, LIU Xin-Cai*. Synthesis and Characterization of Novel Electroactive Polyamide with Azo Groups in the Backbone [J]. Chem. J. Chinese Universities, 2011, 32(8): 1664.
[5]	HUANG Shuang, REN Ai-Min*, LI Zhuo, ZHAO Yang, MIN Chun-Gang. Theoretical Study on Structures and UV-Vis Spectra of Macrocyclic Thiophene Derivatives [J]. Chem. J. Chinese Universities, 2010, 31(3): 553.
[6]	ZHANG Hai-Yan², SHI Hui-Jie¹, SHI Xian-Fa^1. Synthesis and Characterization of p-tert*-Butylcalixarene Derivative Containing Adenine and Its Molecular Recognition to Nucleotides and Bases [J]. Chem. J. Chinese Universities, 2008, 29(9): 1777.
[7]	YANG Li-Guo, YAO Lei, WANG Yong-Guo, BEN Teng*, ZHANG Wan-Jin. Synthesis and Properties of Poly(aryl ether ketone) Macrocyclic Oligomer with Electroactive Groups [J]. Chem. J. Chinese Universities, 2008, 29(3): 655.
[8]	MA Jing¹, ZHENG Xue-Fang^1,2*, TANG Qian^1,2, YANG Yan-Jie^1,2, SUN Xia¹, GAO Da-Bin². Spectroscopic Studies on the Interaction of Cu²⁺ with Myoglobin [J]. Chem. J. Chinese Universities, 2008, 29(2): 258.
[9]	HOU Jun¹, ZHOU Zi-Yan¹, WU Xue¹*, ZHU Dong-Xia², LI Peng² . Synthesis and Properties of Novel Porphyrin [J]. Chem. J. Chinese Universities, 2007, 28(8): 1424.
[10]	MAO Hua-Ping¹, YU You-Hai¹, CHEN Liang¹, LU Xiao-Feng¹, ZHANG Wan-Jin¹, ZHANG Hong-Xing². Synthesis and Characterization of a Novel Azo Compound with ‘Dumbbell Shape’ [J]. Chem. J. Chinese Universities, 2006, 27(10): 1999.
[11]	LIU Jian, LIU Yu, LUO Cui-Ping, LIU En-Hui, YANG Yu-Ping, GAN Quan, ZHU Mei-Xiang, ZHU Wei-Guo. Synthesis of Cyclometalated Platinum Complexes Containing Triarylamino Group and Their Photophysical and Electrochemical Properties [J]. Chem. J. Chinese Universities, 2006, 27(10): 1873.
[12]	ZOU Wu-Xin, TAN Ting-Feng, LI Xu, Meng Ji-Ben . Synthesis and Negative Photochromic Properties of Photochromic Spiropyrans Compounds Supported by Polyethylene Glycol [J]. Chem. J. Chinese Universities, 2005, 26(8): 1471.
[13]	FENG Dong-Dong, ZHUANG Qi-Xin, WU Ping-Ping, HAN Zhe-Wen . A Theoretical Study of UV-Vis Absorption Spectra of Heterocyclic Aromatic Polymers [J]. Chem. J. Chinese Universities, 2005, 26(3): 522.
[14]	PENG Yi, YAN Shi-Ping, LIAO Dai-Zheng, JIANG Zong-Hui, CHENG Peng . Crystal Structures and UV-Vis Spectral Properties of Sulfato and Carbonato Bridged Dinuclear Iron(Ⅲ) Complexes [J]. Chem. J. Chinese Universities, 2004, 25(2): 221.
[15]	LI Xiao-Ling, XU Wei-Qing, JIA Hui-Ying, WANG Xu, ZHAO Bing, LI Bo-Fu . UV-Vis and XPS Spectroccopic Studies on Self-assembled Metalloporphrin Films [J]. Chem. J. Chinese Universities, 2004, 25(11): 2131.

Synthesis of Amino-capped Aniline Pentamer and UV-Vis Spectral Study

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments