Synthesis and Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra(p-Stearyloyloxyphenyl)porphyrin Complexes

Abstract

Abstract: The Fourier transform infrared photoacoustic spectra(FTIR-PAS) of tetra(p-stearyloxyphenyl)porphyrin TSPPH₂ and its complexes of Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) in the range of 3 600-190 cm^-1 were measured and investigated. The bands at 3 318.0 and 968.4 cm^-1 of TSPPH₂ are due to the N-H stretching and in-plane and out-plane bending vibration of the pyrrole groups. All these bands disappear when the complexes are formed. The vibration coupling between the M-N stretching and the porphyrin ring deformation appears at 243 cm^-1. Metal sensitive bands were found at about 1 350, 1 018, 995, 802, 740 and 232 cm^-1.

Key words: Tetra(p-stearyloyloxyphenyl)porphyrin, Complexes, Infrared photoacoustic spectrum

CLC Number:

O614

TrendMD:

SHI Yu-Hua, YAHIRO Nobuhide, LIU Wei, SHI Tong-Shun. Synthesis and Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra(p-Stearyloyloxyphenyl)porphyrin Complexes[J]. Chem. J. Chinese Universities, 2004, 25(7): 1194.

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Synthesis and Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra(p-Stearyloyloxyphenyl)porphyrin Complexes

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