Synthesis of a Novel Sulfonated Poly(ether ether sulfone)s Used as Proton Exchange Membrane Fuel Cell(PEMFC)

Abstract

Abstract: A novel sulfonated poly(ether ether sulfone) derived from 3,3′,5,5′-tetramethylbiphenyl-4,4′-diol was synthesized by direct aromatic nuelecphilic condensation of 3,3′,5,5′-tetramethylbiphenyl-4,4′-diol with various ratios of 3,3′-disulfonate-4,4′-dichlorodiphenylsulfone to 4,4′-dichlorodiphenylsulfone. The polymers have a good thermal stability and solubility in some polar solvents. Most of them can be cast into tough membranes, and the properties of the membranes will be studied in future.

Key words: Sulfonation, Poly(ether ether sulfone)s, Fuel cell, Proton exchange membrane

CLC Number:

O631

TrendMD:

LI Xian-Feng, NA Hui, LU Hui . Synthesis of a Novel Sulfonated Poly(ether ether sulfone)s Used as Proton Exchange Membrane Fuel Cell(PEMFC)[J]. Chem. J. Chinese Universities, 2004, 25(11): 2157.

[1]	QIU Xinsheng, WU Qin, SHI Daxin, ZHANG Yaoyuan, CHEN Kangcheng, LI Hansheng. Preparation and High Temperature Fuel Cell Performance of Ionic Crosslinked Sulfonated Polyimides for Proton Exchange Membranes [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220140.
[2]	CHEN Changli, MI Wanliang, LI Yujing. Research Progress of Single Atom Catalysts in Electrochemical Hydrogen Cycling [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220065.
[3]	LUO Bian, ZHOU Fen, PAN Mu. Study on Preparation and Accessibility of Hierarchical Porous Carbon Supported Platinum Catalyst [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210853.
[4]	JIA Hongjun, ZHANG Jiatao, MA Zhuoli, WANG Heng, YANG Xinyu, YANG Jiazhi. Preparation of PTFE/PAA/Nafion Composite Membrane by Aqueous Polymerization of Acrylic Acid and Its Properties [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220350.
[5]	LIU Jie, LI Jinsheng, BAI Jingsen, JIN Zhao, GE Junjie, LIU Changpeng, XING Wei. Constructing a Water-blocking Interlayer Containing Sulfonated Carbon Tubes to Reduce Concentration Polarization in Direct Methanol Fuel Cells [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220420.
[6]	FU Zhinan, TAN Yunlong, XIAO Guyu, YAN Deyue. Synthesis and Properties of Sulfonated Poly（phthalazinone ether phosphine oxide）s with Perfluorobiphenyl Moieties for Proton Exchange Membranes [J]. Chem. J. Chinese Universities, 2021, 42(8): 2635.
[7]	PU Yangyang, NING Cong, LU Yao, LIU Lili, LI Na, HU Zhaoxia, CHEN Shouwen. Preparation and Characterizations of Cross-linked Sulfonated Poly（ether ether ketone）/Partially Fluorinated Sulfonated Poly（aryl ether sulfone） Blend Membranes [J]. Chem. J. Chinese Universities, 2021, 42(6): 2002.
[8]	CAO Kaiyue, PENG JinWu, LI Hongbin, SHI Chengying, WANG Peng, LIU Baijun. High-temperature Proton Exchange Membranes Based on Cross-linked Polybenzimidazole/hyperbranched-polymer Blends [J]. Chem. J. Chinese Universities, 2021, 42(6): 2049.
[9]	WANG Yuemin, MENG Qinglei, WANG Xian, GE Junjie, LIU Changpeng, XING Wei. Enhancement of Performance of Fe-N-C Catalysts by Copper and Sulfur Doping for the Oxygen Reduction Reaction [J]. Chem. J. Chinese Universities, 2020, 41(8): 1843.
[10]	LIANG Minhui, WANG Peng, LI Hongbin, LI Tianyang, CAO Kaiyue, PENG Jinwu, LIU Zhenchao, LIU Baijun. Preparation of High-temperature Proton Exchange Membranes Based on Semi-interpenetrating Polymer Networks [J]. Chem. J. Chinese Universities, 2020, 41(12): 2845.
[11]	HUA Tao, LI Shengnan, LI Fengxiang, WANG Haonan. Treatment of Naphthalene by Microbial Electrochemical System and the Analysis of Microbial Communities ^† [J]. Chem. J. Chinese Universities, 2019, 40(9): 1964.
[12]	CHENG Qinwen, YUAN Bo, ZHU Xiangdong, ZHANG Kai, ZHANG Xingdong. Surface Elemental Compositions and in Vitro Bioactivities of the PEEK Materials with Various Sulfonation and Alkali Treatments [J]. Chem. J. Chinese Universities, 2019, 40(8): 1757.
[13]	YU Yancun, WANG Xian, GE Junjie, LIU Changpeng, XING Wei. Promoted Formic Acid Electrooxidation Using PdN_x/C Catalyst Prepared with Hyperbranched Polymer^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1433.
[14]	SONG Xipeng, LIU Jinyu, WANG Lihua, HAN Xutong, HUANG Qinglin. Preparation of Polybenzimidazole/Polyvinylpyrrolidone Proton Exchange Membranes for Vanadium Redox Flow Battery^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1543.
[15]	LIN Zhouchen,HUANG Qiaoxi,LEI Ming. Fabrication and Electrocatalytic Performance of Graphene-fullerene Ammonium Iodide Composite Supported Pd Nanocatalyst for Ethanol Oxidation^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 1013.

Synthesis of a Novel Sulfonated Poly(ether ether sulfone)s Used as Proton Exchange Membrane Fuel Cell(PEMFC)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments