Studies on Deformation and Dissolution Behavior of Porous Nickel During the Oxidation/Lithiation in Molten Carbonates

Abstract

Abstract: Based on the previous work, the deformation of porous nickel with time during the oxidation/lithiation in molten carbonates at 923 K under mix atmospheres was measured, under loading and without loading, respectively. The morphology of nickel samples after testing for different time was characterized by SEM. And the corresponding concentration of nickel ions dissolving in molten carbonates was detected by Atomic Adsorption Spectrometry(ABS). The results indicate that there was a severe dissolution of nickel during the oxidation/lithiation of porous nickel under loading condition, in addition, even if without loading, the dissolution of nickel from porous nickel was still obvious.

Key words: Porous nickel, In situ oxidation/lithiation, Dissolution, Molten carbonate

CLC Number:

TrendMD:

CHEN Li-Jiang, LIN Chang-Jian, FENG Zu-de, CHENG Xuan . Studies on Deformation and Dissolution Behavior of Porous Nickel During the Oxidation/Lithiation in Molten Carbonates[J]. Chem. J. Chinese Universities, 2003, 24(3): 496.

[1]	TAN Lejian, ZHONG Xuanshu, WANG Jin, LIU Zongjian, ZHANG Aiying, YE Lin, FENG Zengguo. Low Critical Dissolution Temperature Behavior of β⁃Cyclodextrin and Its Application in the Preparation of β⁃Cyclodextrin Sheet Crystal with Ordered Nano⁃channel [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220405.
[2]	WANG Xiao,JIN Biao,WANG Yubin,XU Zhuoyue,ZHANG Lu,ZHANG Xiaoting,YANG Liushuan. Interaction Mechanism of Anions in Hydrothermal Crystallization of Desulfurization Gypsum Whiskers ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 473.
[3]	HE Zijun,XIAO Ming,MA Xiangying,QIU Jiangyuan,XIAO Biyuan,QIN Fanghong,HUANG Zaiyin. Facet and Temperature Effects on Dissolution Thermodynamic Functions of Ag₃PO₄ Microcrystals^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 959.
[4]	QIN Fanghong,QIU Jiangyuan,XIAO Biyuan,MI Yan,HUANG Zaiyin. Investigation into the Thermodynamic Properties of Nano-silver Halides Based on the Principle of Dissolution Thermodynamics^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2214.
[5]	JIANG Xue, SHI Nannan, ZHANG Ying, CHENG Kui, YE Ke, WANG Guiling, CAO Dianxue. Influence of LiBOB on the Electrochemical Performance of Li_1.15Ni_0.68Mn_1.32O₄ Electrode^† [J]. Chem. J. Chinese Universities, 2015, 36(4): 739.
[6]	YU Fei, XI Ting-Fei, ZHANG Shu-Jiang, ZHANG Zhi-Xiong, LAI Chen. Preparation of Chitosan Lactate Sponges with Uniform Vertical Pores and Fitted Analysis of Release Medicine Model in vitro [J]. Chem. J. Chinese Universities, 2012, 33(04): 843.
[7]	LIU Yu-Pu, DI You-Ying*, HE Dong-Hua, KONG Yu-Xia, YANG Wei-Wei, DAN Wen-Yan. Low-temperature Heat Capacities and Thermochemistry Properties of Ethylene Diamine Dihydrochloride [J]. Chem. J. Chinese Universities, 2010, 31(6): 1227.
[8]	WANG Mei-Ling, ZANG Hong-Jun*, CAI Bai-Xue, CHENG Bo-Wen. Dissolubility of the Cellulose in [AMMor]Cl/[AMIM]Cl [J]. Chem. J. Chinese Universities, 2009, 30(7): 1469.
[9]	GUO Li-Ying, SHI Tie-Jun^*, LI Zhong, DUAN Yan-Peng, WANG Yu-Gang. Synthesis of Novel and Functionalized Ionie Liquid [HeEIM]Cl and Its Solubility for Cotton Fibre [J]. Chem. J. Chinese Universities, 2008, 29(9): 1901.
[10]	WANG Zheng*, YANG Ji, GAO Zhao. Studies on Degradable Poly(ether-anhydride) Photocrosslinked Gels to Increase the Solubility of Poorly Water-soluble Drugs [J]. Chem. J. Chinese Universities, 2007, 28(5): 987.
[11]	CHEN Guo-Liang^1,2, ZHOU Jian-Zhang¹, LIN Zhong-Hua¹, LU Jiang-Hong², LIN Jin-Mei². EQCM Study of Effect of Allyl Thiourea on Anodic Dissolution and Cathodic Deposition of Cu in Acidic Media [J]. Chem. J. Chinese Universities, 2006, 27(9): 1699.
[12]	CHEN Li-Jiang, CHENG Xuan, LIN Chang-Jian, HUANG Chao-Ming. Investigations on Dissolution Mechanism of the NiO Cathode Materialsin MCFC by In-situ Raman Spectroscopy [J]. Chem. J. Chinese Universities, 2002, 23(4): 661.
[13]	LIU Hou-Tian, LIANG Hai-He, YANG Jiong, ZHOU Wei-Fang. The Growth Mechanism of the Anodic Pb(Ⅱ) Film Formed on Lead-tin Alloy in Sulfuric Acid Solution [J]. Chem. J. Chinese Universities, 2002, 23(1): 116.
[14]	CHEN Ming, LI Yuan-Chang, HONG Xiao-Yin, JIAO Xiao-Ming, CHENG Ai-Ping. Image Reversal Techniques with a Water-based Chemical Amplified Photoresist [J]. Chem. J. Chinese Universities, 2000, 21(9): 1485.
[15]	LEI Jing-Lei, LUO Jiu-Li  . A Dynamic Model of Potentiostatic Current Oscillation of Copper Electrodissolution in Acidic Chloride Solution [J]. Chem. J. Chinese Universities, 2000, 21(3): 453.

Studies on Deformation and Dissolution Behavior of Porous Nickel During the Oxidation/Lithiation in Molten Carbonates

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments