Encapsulation and Catalytic Activity of Lipophilic Soluble Metallophthalocyanine Derivative in MCM-41

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (8): 1275.

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Encapsulation and Catalytic Activity of Lipophilic Soluble Metallophthalocyanine Derivative in MCM-41

BAI Ni¹, ZHANG Ping¹, GUO Yang-Hong¹, PANG Wen-Qin¹, SONG XI-Ming², CHEN Hong-Mei², LI Biao², CHANG Xiao-Hong²

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China;
2. Department of Chemistry, Liaoning University, Shenyang 110036, China

Received:2000-08-29 Online:2001-08-24 Published:2001-08-24

Abstract

Abstract: Lipophilic soluble metallophthalocyanine derivative Co(Ⅱ)-4,4',4″,4"-tetrapropy-loxycarbonyl phthalocyanines CoPc[COO(C₃H₇)₄)₄] has been encapsulateDInto MCM-41 by impregnation wetness method, then the composites were characterized by XRD, UV-Vis diffuse reflectance spectra, TGA-DTA, Raman spectrum and N₂ adsorption methods. At last, their catalytic properties on the oxidation of 2-mercaptoethanol have been examined. Compared to bulk metallophthalocyanine molecule, excellent catalytic properties have been shown for the composite.

Key words: Mesoporous molecular sieve MCM-41, Metallophthalocyanine derivative, Encapsulation, Catalytic acticvity

CLC Number:

O614

TrendMD:

BAI Ni, ZHANG Ping, GUO Yang-Hong, PANG Wen-Qin, SONG XI-Ming, CHEN Hong-Mei, LI Biao, CHANG Xiao-Hong. Encapsulation and Catalytic Activity of Lipophilic Soluble Metallophthalocyanine Derivative in MCM-41[J]. Chem. J. Chinese Universities, 2001, 22(8): 1275.

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Encapsulation and Catalytic Activity of Lipophilic Soluble Metallophthalocyanine Derivative in MCM-41

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