Studies on the Two Photon Absorption Cross-sections of trans-Stilbene Derivatives

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (7): 1197.

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Studies on the Two Photon Absorption Cross-sections of trans-Stilbene Derivatives

REN Ai-Min¹, FENG Ji-Kang¹, ZHAO Xian², LIU Chun-Ling³, SU Zhong-Min⁴

1. The National Key Laboratory of Theoreticaland Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun, 130023;
2. The National Key Laboratory of Cry stal Materials, Sandong University, Jinan, 250100;
3. Instituteof Opto-Electronics, National Key Laboratory of Tunable Laser Technology, Harbin, 150001;
4. Institute of Function Material Chemistry, Northeast Normal University, Changchun, 130024

Received:2000-07-14 Online:2001-07-24 Published:2001-07-24

Abstract

Abstract: The geometry, electronic structures and electronic spectra of trans-stilbene derivatives are systematically studied by PM3 and INDO/CImethods. On the basis of correct UV-Vis spectra, the position and strength of the two photon absorption cross-sections can be predicted. We deviced a program of Sum Over-States expression and calculated the nonlinear third-order optical susceptibilities and two photon absorption cross-sections by it. The influences of various substituents on two photon absorption cross-sections are discussed micromechanically.

Key words: Stilbene derivative, Electronic spectra, Two photon absorption cross section

CLC Number:

O641.12

TrendMD:

REN Ai-Min, FENG Ji-Kang, ZHAO Xian, LIU Chun-Ling, SU Zhong-Min . Studies on the Two Photon Absorption Cross-sections of trans-Stilbene Derivatives[J]. Chem. J. Chinese Universities, 2001, 22(7): 1197.

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Studies on the Two Photon Absorption Cross-sections of trans-Stilbene Derivatives

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