Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (4): 610.

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Preparation and Characterization of Nanometer Photocatalysis SnO2@TiO2

YAN Xiu-Ru, LI Xiao-Hong, SONG Kuan-Xiu, ZHAO Hai-Tao, CHEN Xiu-Zeng   

  1. Department of Chemistry, School of Sciences, Tianjin University, Tianjin 300072, China
  • Received:2000-04-04 Online:2001-04-24 Published:2001-04-24

Abstract: SnO2@TiO2 coated particles have been prepared with Ti(OC4H9)4 by hydrolysis cross link TiO2 on active SnO2 hydrated particle. Its morphology and structure were characterized by XRD, TEM, and BETmethod. In order to improve the photocatalytic degradation activity of SnO2@TiO2 for dichlorvos, the conditions of preparing were selected and the better photocatalytic activity were received. The result indicated that: SnO2@TiO2 was composited with ranatase TiO2 and rutile SnO2. When mass fraction of TiO2 in SnO2@TiO2 is 56.45%, water content in SnO2 alcohol solution is 20%, volume fraction of Ti(OC4H9)4 in alcohol solution is 34.5%, and ignition temperature of SnO2@TiO2 is 680 ℃, the best photocatalytic activity of SnO2@TiO2 were received. The other factors of effect of SnO2@TiO2 photocatalytic activity were given.

Key words: Nanometer, Active particle layer coated method, Coated photocatalyst, SnO2@TiO2

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