Abstract:

A new perchlorinated fused compound, 6-(p-tolyl)-6H-decachloro-benzo[cd]-pyrene 1, was synthesized with solvothermal reaction,a novel approach developed in our group. 1 is an interesting molecule for it is similar in structure to chlorinated fragment molecules of fullerenes^[1]. Besides, its homologues such as 6-methyl-6H-benzo[cd]pyrenes, 6-methoxycarbonyl-6H-benzo[cd]pyrene and 6-mesyloxyl-6H-benzo[cd]pyrene[2] have been synthesized as parent hydrocarbons of benzo[cd]pyrenyl system, which were investigated for its NBMO properties^[3].