Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (S1): 494.
• Synthetic Sciences • Previous Articles Next Articles
XIE Tong1,2, WU Xiao-Li1, LIU Wan-Yi1, GAO Shi-Yang2, MA Yong-Xiang1
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Abstract:
There is currently considerable interest in the synthesis of new material with large second-order optical nonlinearities[1-2]. Ferrocenyl derivatives that we synthesized should offer the nonlinear optical properties because they possess (-donor acceptor interactions and non-centrosymmetry. In these compounds, ferrocenyl moiety is strong donor and pyridinium moiety can provide low-lying (* acceptor orbitals. Furthermore, these ferrocenyl compounds may also be used in preparation of self-assembled monolayers (SAMs)[3] due to their long alkyl chain that can be anchored on metal oxide by carboxylic group. The synthesis of ferrocenyl derivatives is shown in Scheme 1.
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XIE Tong, WU Xiao-Li, LIU Wan-Yi, GAO Shi-Yang, MA Yong-Xiang. The Synthesis of Ferrocenyl Compounds with Nonlinear Optical Properties[J]. Chem. J. Chinese Universities, 2000, 21(S1): 494.
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http://www.cjcu.jlu.edu.cn/EN/Y2000/V21/IS1/494