CJCU

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (S1): 493.

• Synthetic Sciences • Previous Articles     Next Articles

Synthesis and Crystal Structure of Molybdenum-Sulfur Cluster Compounds Coordinated by Nicotinic Acid and Isonicotinic Acid

QIN Ye-Yan, WU Ling, TANG Yan-Hong, KANG Yao, LI Zhao-Ji, YAO Yuan-Gen   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002
  • Online:2000-12-31 Published:2000-12-31
  • Contact: YAO Yuan-Gen
  • Supported by:

    Supported by the National Natural Science Foundation of China (No.29303025 and No.29733090).

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Abstract:

Cuboidal Molybdenum have been paid much attention due to their structural resemble with those metallic centers in some biological systems[1]. To explore the chemistry of trinuclear Mo-S cluster complexes[2], we rationally synthesized two compounds:Mo3S4(DTP)3(nicotinate)(Py)·EtOH (Ⅰ) (DTP=diethyl dithiophosphate) and Mo3S4(DTP)3(isonicotinate)(Py)·EtOH (Ⅱ) by the substitution reaction of Mo3S4(DTP)3(L)(Py) (L=ClCH2COO-, CH3COO-) with nicotinic acid and isonicotinic acid, respectively.

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