CJCU

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (S1): 492.

• Synthetic Sciences • Previous Articles     Next Articles

Dimerization of Incomplete Cubane-Type Mo3S4(DTP)3 Units Linked by Bridging α, ω-Dicarboxylate

TANG Yan-Hong, WU Ling, QIN Ye-Yan, KANG Yao, LI Zhao-Ji, YAO Yuan-Gen   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002
  • Online:2000-12-31 Published:2000-12-31
  • Contact: YAO Yuan-Gen
  • Supported by:

    Supported by the National Natural Science Foundation of China (No.29303025 and No.29733090).

PDF (PC)

Abstract:

Since the trinuclear molybdenum cluster compound Mo3S4(DTP)3(μ-DTP)(L) (DTP=diethyldithiophosphate, L=loosely-coordinated ligand) was reported[1],a large number of monomeric trinuclear molybdenum derivatives have been synthesized from it by its diverse substitution reactions[2]. This reaction provides a useful route to design cluster complexes with specific functions. By the reaction with α, ω-dicarboxylates, we successfully synthesized the first oligomer containing two incomplete cubane-type[Mo3S4] cores formulated as[Mo3S4(DTP)3(DMF)]2[η2-μ-OOC(CH2)3COO-μ-η2]) whose molecule structure is as follows:

TrendMD: