CJCU

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (S1): 443.

• Synthetic Sciences • Previous Articles     Next Articles

Cation-π Interactions:Synthesis and Crystal Structure of Complex:[Na(DB18C6)]2[Pd(SCN)4]

LIU Ying1, DOU Tian-Min1, ZHANG Rong-Lan1, DAI Ji-Cui1, LI Xue2, ZHENG Pei-Ju2   

  1. 1. Department of Chemistry, Liaocheng Teacher's University, Liaocheng 252000;
    2 Research Center of Analysis and Measurement, Fudan University, Shanghai 200433
  • Online:2000-12-31 Published:2000-12-31

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Abstract:

The cation-π interactions have attracted much attention as an important noncovalent binding force. We have synthesized and characterized the first example[K(DB 18C6)]2[Pd(SCN)4] which exist K+-π interactions in crown ether compounds[1]. However,the reported Na+ complexes structurally characterized by X-ray diffraction analysis have so far been limited to a few compounds. We now report the structure of complex:[Na(DB18C6)]2[Pd(SCN)4] which also exist Na+-n interactions.

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