Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (S1): 268.
• Chemistry in Materials Sciences • Previous Articles Next Articles
YANG Wen-Bin, LU Can-Zhong, LIN Xiang, ZHUANG Hong-Hui
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The authors thank the Chinese Academy of Sciences and the State Education Ministry for financial support.
Abstract:
Due to the variety of their components, structures and properties, significant attention continues to be focused on the polyoxometalatic anions in many research fields such as catalysis, biology, medicine and materials science1. When the aqueous solution of Na2WO4·2H2O was reduced by iron powder in CH3COOH (30%), crystals of Na5[Fe2.5(H2O)10W12O42]·ca.32 H2O 1, which crystallizes in the triclinic space group P 1 with a=12.121(2), b=12.426(3), c=l3.247(3) Å, α=68.33(3), β=71.33(3), γ=71.44(3)° and Z=l, precipitated after several weeks.
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YANG Wen-Bin, LU Can-Zhong, LIN Xiang, ZHUANG Hong-Hui. A Novel Ferroferric Polyoxotungstate:Synthesis, Structure and Magnetic Properties of Na5[Fe2.5(H2O)10W12O42]·ca.32 H2O[J]. Chem. J. Chinese Universities, 2000, 21(S1): 268.
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http://www.cjcu.jlu.edu.cn/EN/Y2000/V21/IS1/268