Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (S1): 179.
• Chemistry in Life Sciences • Previous Articles Next Articles
CAO Li-Xin, ZHOU Ban-Xne
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This work was supported by a science grant from Shandong province (Grant No. Y98B02021).
Abstract:
Chromium(Ⅲ) is one essential nutrient that has been implicated as glucose tolerant factor(GTF) in the maintenance of normal carbohydrate and lipid metabolism. Schiff base complexes of chromium (Ⅲ) such as N,N' -ethylenebis (Salicylideneiminato) diaquochromium (Ⅲ) chloride[Cr(Salen)(H2O)2]Cl as a new kind of GTP model was shown to reduce the symptoms of diabetes significantly, hyperglycemia and cholesterol in diabetic rates[l]. After studied the decomposition and characterization of[Cr(Salen)(H2O)2]Cl[2], a new confound of[Cr(Salen)(H2O)2]BPh4 is prepared and its transfer Gibbs energies(Δtr Go) from water to strait-chain Alkanols is studied in order to understand the thermodynamic properties of[Cr(Salen)(H2O)2]+ in different solvents.
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CAO Li-Xin, ZHOU Ban-Xne. Transfer Gibbs Energies of[Cr(Salen)(H2O)2]BPh4 From Water to Straight-chain Alkanol[J]. Chem. J. Chinese Universities, 2000, 21(S1): 179.
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http://www.cjcu.jlu.edu.cn/EN/Y2000/V21/IS1/179