Free Radical Ternary Copolymerization of C60 with Styrene and Maleic Anhydride

Abstract

Abstract: Anovel C₆₀-styrene-maleic anhydride copolymer was prepared with radical polymerization. 50 mg of C₆₀ and 1 g of styrene and 1 g of maleic anhydride were dissolved in₂₀ mLof o-dichlorobenzene, then was initiated by 200 mg of BPOat 70 ℃ under the protection of Ar for 32 h. The copolymer was obtained as a brown solid. The structure of copolymer was characterized by UVand FTIR. GPCanalyses shows that its average molecular weight M_w is 13000. The copolymer is soluble in THF, DMSOand water. The surface tension of 0.5% of copolymer aqueous solution was determined to be 54.6×10^-3N/m(20 ℃). TEManalyses shows that the copolymer is a kind of water-soluble nanosphere with the average diameter of about 60 nm.

Key words: C₆₀, Free radical copolymerization, Water-soluble nanosphere

CLC Number:

O631

TrendMD:

GUAN Wen-Chao, LEI Hong, LIAO Dao-Xun. Free Radical Ternary Copolymerization of C₆₀ with Styrene and Maleic Anhydride[J]. Chem. J. Chinese Universities, 2000, 21(7): 1149.

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Free Radical Ternary Copolymerization of C₆₀ with Styrene and Maleic Anhydride

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