Synthesis of Perchlorinated Polycyclic Aromatic Hydrocarbon by Laser Ablation

Abstract

Abstract: By laser ablating graphite in the vapor of tetrachloromethane, a series of perchlorinated polycyclic aromatic hydrocarbons were synthesized. Among them, hexachlorobenzene (C₆Cl₆), octachloronaphthalene (C₁₀ Cl₈), octachloroacenaphthylene (C₁₂ Cl₈), decachloroanthracene (C₁₄ Cl₁₀), decachlorophenanthrene (C₁₄ Cl₁₀ ), decachloropyrene (C₁₆ Cl₁₀ ), decachlorofluoranthene (C₁₆Cl₁₀ ), C₁₈ Cl₁₀, C₂₀Cl₁₀, C₂₂Cl₁₂ and C₂₄Cl₁₂ were identified by HPLC-UV-MS. The results demonstrate the potential of the reaction for synthesizing the compounds with special structures.

Key words: Laser ablation, Synthesisl Perchlorinated polycyclic aromatic hydrocarbon

CLC Number:

O644.18

TrendMD:

ZHOU Yi-Nan, XIE Su-Yuan, CHEN Hong, HUANG Rong-Bin, ZHENG Lan-Sun . Synthesis of Perchlorinated Polycyclic Aromatic Hydrocarbon by Laser Ablation[J]. Chem. J. Chinese Universities, 2000, 21(5): 789.

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Synthesis of Perchlorinated Polycyclic Aromatic Hydrocarbon by Laser Ablation

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