A Study of Mn-Se and Mn-O-Se Cluster Ions Using Mass-spectrometry

Abstract

Abstract: Time-of-flight mass spectrometry was used to study Mn-Se and Mn-O-Se cluster ions produced by laser direct vaporization of solid samples. In Mn-Se binary cluster ions, (MuSe)_n⁺ is the main composition of positive cluster ions, while [(MuSe)nSe]^- is the main composition of negative cluster ions. When a mass-selected (MuSe)_n⁺ was photolyzed, the photolysls produt ions have the same general composition (MuSe)_m⁺. In Mn-O-Se ternary system, the main positive cluster ions produced are Mn-Obinary clusters, in which [(MnO)n]+ has a high intensity, while the negative cluster ions include Se_n^-,[SenO]^-, [SenO₃]^- and [MnSe_n]^-. It seems that the cluster ions were produced by the vaporization of solid sample and this conforms to a gas-phase aggregation mechanism.

Key words: Atomic clusters, Laser ablation, Tandem time-of-flight mass spectrometer, Ultraviolet photolysis

CLC Number:

O657.6

TrendMD:

CHEN Yun-Qing, XING Xiao-Peng, LIU Peng, ZENG Rong, GAO Zhen, ZHU Qi-He . A Study of Mn-Se and Mn-O-Se Cluster Ions Using Mass-spectrometry[J]. Chem. J. Chinese Universities, 2000, 21(5): 743.

[1]	ZHANG Dan, FENG Liuxing, WANG Jun, SHEN Dairui, XIONG Jinping. Quantitative Analysis of Proteins in Human Serum by Species-unspecific Isotope Dilution-gel Electrophoresis-laser Ablation-inductively Coupled Plasma Mass Spectrometry^† [J]. Chem. J. Chinese Universities, 2014, 35(9): 1889.
[2]	TIAN Fei, AN Jun-Chao, CAO Hong-Mei, GUO Shi-Zhen, SUN Jing. High Yield NiO Nanocubes from Bulk Nickel by Millisecond Pulse Width Laser Ablation [J]. Chem. J. Chinese Universities, 2013, 34(8): 1965.
[3]	KE Yu-Qiu, ZHANG Lu-Yuan, CHAI Xin-Na, ZHENG Hong-Tao, JIN Lan-Lan, HU Sheng-Hong. Elemental Signal Response of Sulfide Minerals in LA-ICP-MS Microanalysis [J]. Chem. J. Chinese Universities, 2012, 33(02): 257.
[4]	HE Jian^1, HUANG Rong-Fu², YU Quan², HANG Wei^1,2, HUANG Ben-Li². Standardless Semi-quantitative Elemental Analysis of Steel Using Laser Ablation Time-of-flight Mass Spectrometry [J]. Chem. J. Chinese Universities, 2009, 30(1): 57.
[5]	ZHUANG Ke, XIAO Ke, WANG Guo-Jie, JIANG Lei . Control of Thermally Induced Pattern Formation in Bilayer Metal/Polymer Films [J]. Chem. J. Chinese Universities, 2004, 25(1): 157.
[6]	ZHANG Yi, CHEN Wen-Zhe, ZHANG Wen-Gong. Studies on Nano-cobalt/Ethanol Sol Prepared by Pulsed Laser Ablation [J]. Chem. J. Chinese Universities, 2003, 24(2): 337.
[7]	XING Xiao-Peng, ZHAO Xiang, ZHANG Xia, GAO Zhen  . Mass Spectrometric Study of Ag/Se Cluster Ions and Reaction of Ag and Se Clusters [J]. Chem. J. Chinese Universities, 2002, 23(3): 428.
[8]	CHEN Yun-Qing, XING Xiao-Peng, GAO Zhen, ZHU Qi-He . Formation and Photodissociation of Copper-selenium Clusters [J]. Chem. J. Chinese Universities, 2002, 23(11): 2147.
[9]	WANG Ying, QIN Qi-Zong . A Nanocrystalline NiO Thin Film Prepared by Pulsed Laser Ablation [J]. Chem. J. Chinese Universities, 2002, 23(11): 2043.
[10]	HAN Chun-Ying, XING Xiao-Peng, GAO Zhen, ZHU Qi-He . Formation and Photodissociation of Chromium/Phosphorus Binary Clusters [J]. Chem. J. Chinese Universities, 2001, 22(4): 622.
[11]	ZHOU Yi-Nan, XIE Su-Yuan, CHEN Hong, HUANG Rong-Bin, ZHENG Lan-Sun . Synthesis of Perchlorinated Polycyclic Aromatic Hydrocarbon by Laser Ablation [J]. Chem. J. Chinese Universities, 2000, 21(5): 789.
[12]	ZENG Rong, LIU Jian-Bo, HAN Chun-Ying, GAO Zhen  . Formation by Laser Ablation, Photodissociation and Structure Analysis of C/P Binary Clusters [J]. Chem. J. Chinese Universities, 2000, 21(4): 581.
[13]	TANG Yong-Xin, DANG Hai-Jun, ZHANG Zhuang-Jian, QIN Qi-Zong . A Quadrupole Mass Spectrometric Study on Pulsed Laser Ablation of Y₁Ba₂Cu₃O_7-δ [J]. Chem. J. Chinese Universities, 1999, 20(2): 286.
[14]	CHEN Mo-Hua, WANG Xue-Feng, ZHANG Lu-Ning, QIN Qi-Zong . Reaction Products of 532nm Laser Ablation of Ta with Carbon Dioxide Studied by Matrix Isolation Infrared Spectroscopy [J]. Chem. J. Chinese Universities, 1999, 20(10): 1619.
[15]	XU Can, ZHANG Rong-Jun, ZHU Lei, ZHAO Li, QIAN Shi-Xiong, LI Yu-Fen, LONG Ying-Cai. The Generation Mechanism of Gaseous [(SiO₂)_nX]^- Clusters [J]. Chem. J. Chinese Universities, 1997, 18(6): 943.

A Study of Mn-Se and Mn-O-Se Cluster Ions Using Mass-spectrometry

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments