Studies on Complexation-induced Micellization of Block-graft Copolymer SEPG and PS(OH)

Abstract

Abstract: The complexation in toluene between SEPG, which was prepared by atom transfer radical polymerization(ATRP) with a block-graft architecture, and PS(OH) via hydrogen-bonding was investigated by viscometry and laser light scattering(LLS). In the process of complexation the soluble complex-micelles were formed. The viscosity measurements confirm the stable micellization based on hydrogen bonding. The LLS results revealed the dependence of the size and its distribution of the complex-micelles on both hydroyl content in PS(OH) and blend composition.

Key words: Hydrogen-bonding, Complexation, Micellization

CLC Number:

O631

TrendMD:

PAN Quan-Ming, LIU Shi-Yong, XIE Jing-Wei, JIANG Ming . Studies on Complexation-induced Micellization of Block-graft Copolymer SEPG and PS(OH)[J]. Chem. J. Chinese Universities, 2000, 21(11): 1751.

[1]	HU Xueyi, CHEN Miaomiao, FANG Yun, FENG Ruiqin, HAN Huihui. Investigation on Pseudo-polyanions of Cationic Cellulose-Sodium Dodecylbenzenesulfonate^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1464.
[2]	ZHANG Xiaotao,WANG Yan’an,HUI Jia,SHI Yan,FU Zhifeng,YANG Wantai. Reversible-deactivation Radical Solution Polymerization of Methyl Methacrylate Catalyzed by Tetrabutylammonium Iodide^† [J]. Chem. J. Chinese Universities, 2019, 40(2): 366.
[3]	CAO Xiaoqiang, YAN Bingqi, WANG Qian, WANG Yaping, QIU Jun, HUANG Yongqing, LI Lin, ZHANG Yan, HU Shugang, KANG Ling, LÜ Xianjun. Adsorption of Cr(Ⅵ) from Aqueous Solutions on Organic Modified Laponite^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 173.
[4]	LI Liangyi, LI Zhanwei, FU Cuiliu, SUN Zhaoyan, AN Lijia. Computer Simulation of Micellization for Ring-like Block Copolymers^† [J]. Chem. J. Chinese Universities, 2014, 35(1): 168.
[5]	LI Dan, JIN Bao-Kang. Study on the Electrochemical Redox Mechanism of 2-Hydroxy-1,4-naphthoquinone [J]. Chem. J. Chinese Universities, 2013, 34(8): 1959.
[6]	XIE Yu, LÜ Zhong-Yuan, SUN Zhao-Yan, AN Li-Jia. Dissipative Particle Dynamics Simulation Study on the Micellization and Gelation Behavior of PEO-PPO-PEO Solution [J]. Chem. J. Chinese Universities, 2013, 34(6): 1454.
[7]	ZHOU Ying-Jie, ZHU Hai-E, ZHANG Jun, WU Shui-Lin, YI Chang-Feng, XU Zu-Shun. Preparation and Micellization Behavior of Europium-containing Fluorescent Amphiphilic Graft Copolymer [J]. Chem. J. Chinese Universities, 2013, 34(3): 732.
[8]	HUANG Jia-Hua, GONG Zhen-Bin, LIN Ji-Jun, DUAN Hua-Ling. Measurement of Complexation Stability Constant and Coordinating Number of Poly(ethylenimine) with Metals [J]. Chem. J. Chinese Universities, 2012, 33(12): 2633.
[9]	MENG Ling-Min, HUANG Qing-Rong, DENG Jing, WU Yi-Jie, SHI Tong-Fei. Micellization of PAA-F108-PAA Block Copolymer Using NMR Spectroscopy [J]. Chem. J. Chinese Universities, 2012, 33(07): 1624.
[10]	HAN Yi-De, DU Yu, LI Yi, SONG Xiao-Wei, YU Ji-Hong, XU Ru-Ren. Synthesis, Structure and Surface Photovoltage Characterization of [Co(en)₃]₂(Zr₂F₁₂)(ZrF₆H₂O)稨₂O [J]. Chem. J. Chinese Universities, 2012, 33(05): 876.
[11]	LIU Guo-Qiang, LI Xiao-Long, XIONG Sheng-Dong, XU Zu-Shun. Preparation and Research on Micellization Behavior of Thermo-sensitive Fluorine-containing Amphiphilic Graft Copolymer [J]. Chem. J. Chinese Universities, 2012, 33(03): 624.
[12]	GUO Kai, SUN Liang, WU Meng-Chun, WANG Shao-Dan, WANG Li-Yan*. Effects of Inclusion Complexation and Degree of Protonation on Cloud Point of Poly(N-acryloyl-N′-propylpiperazine) [J]. Chem. J. Chinese Universities, 2011, 32(9): 2223.
[13]	LU Wen-Ting, LUO Yun-Jun*, LI Guo-Ping, ZHANG Xin-Qian, JIN Yu-Juan. Preparation and Characterization of Pd Nanoclusters Templated by PAMAM Dendrimers [J]. Chem. J. Chinese Universities, 2009, 30(7): 1459.
[14]	TIAN Wei, FAN Xiao-Dong^*, LIU Tao, LIU Yu-Yang, SUN Le, JIANG Min, HUANG Yi. Molecular Inclusion Complexation and Recognition Behavior of Amphiphilic Hyperbranched Polymer Carrying β-Cyclodextrin as Pendant Groups on Shell Layer [J]. Chem. J. Chinese Universities, 2009, 30(3): 632.
[15]	LIU Hong¹, GU Zheng-Biao^1,2*, HONG Yan¹, LI Zhao-Feng^1,2. Complexation of γ-Cyclodextrin with Bromocresol Green [J]. Chem. J. Chinese Universities, 2008, 29(9): 1773.

Studies on Complexation-induced Micellization of Block-graft Copolymer SEPG and PS(OH)

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments