Studies on Synthesis and Electrochemical Activity of Oxadiazole Derivatives Incorporting Thiophene Ring

Abstract

Abstract: A series of novel oxadiazole derivatives containing π-excessive five-memberd ring heterocycle-thiophene(R—OXD) have been prepared as the electron transport layer in organic electroluminescent (OEL) devices. Their molecule structures were characterized by ¹H NMR and elemental analysis. The results of cyclic voltammetry measurements imply that all these R—OXD but F OXD have a higher electron affinity( E_A) than 2-(4-biphenyl)-5-(t-butylphenyl) 1,3,4 oxadiazole(PBD) which implies that they are better electron acceptors than PBD. So they are potentially better materials as the electron transfer.

Key words: Thiophene, Oxadiazole derivatives, Electron affinity

CLC Number:

O646

TrendMD:

ZHANG Zhi-Ming, LI Guo-Wen, MA Yu-Guang, WU Fang, TIAN Wen-Jing, SHEN Jia-Cong . Studies on Synthesis and Electrochemical Activity of Oxadiazole Derivatives Incorporting Thiophene Ring[J]. Chem. J. Chinese Universities, 2000, 21(11): 1719.

References

Related Articles 15

[1]	DAI Wei, HOU Hua, WANG Baoshan. Theoretical Investigations on the Electronic Structures and Reactivity of Heptafluoro-iso-butyronitrile Anion [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220044.
[2]	LI Ran, ZHANG Xudong, MU Lidan, SUN Tong, AI Ganggang, SHA Yelong, ZHANG Yuqi, WANG Jijiang. Preparation and Application of Triplethiophene Derivative Functionalized SiO₂ Inverse Opal Photonic Crystal Fluorescent Films [J]. Chem. J. Chinese Universities, 2021, 42(9): 2989.
[3]	ZHANG Renli, WANG Yao, YU Zhiquan, SUN Zhichao, WANG Anjie, LIU Yingya. Molybdenum Peroxide Anchored on Fluoronated UiO-66 as Catalyst in the Oxidation of Sulfur Containing Compounds [J]. Chem. J. Chinese Universities, 2021, 42(6): 1914.
[4]	WANG Ying, SUN Chuanyin, WANG Runwei, ZHANG Zhendong, ZHANG Daming, ZHANG Zongtao, QIU Shilun. Preparation of Amphiphilic Ti/ZSM-5 Zeolite and Its Catalytic Performance in Oxidative Desulfurization^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1265.
[5]	CHEN Hong,DU Yonghui,ZHANG Xin,LIU Wenyan,ZHOU Xiaoming. Preparation and Electrochemical Properties of Poly(3-hexylthiophene)-coated Lithium-rich Layered Cathode Material Li_1.18Ni_0.15Co_0.15Mn_0.52 $O 2 †$ [J]. Chem. J. Chinese Universities, 2019, 40(4): 777.
[6]	QU Xingxing, DAI Yuyu, LI Weijun, OUYANG Mi, ZHANG Cheng. Synthesis and Electrochromic Properties of Thiophene-carbazol-benzene Derivativies^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1699.
[7]	ZHAO Bangtun, TAO Jingjing, CHEN Xiaoji, FU Huimin, ZHU Weimin. Synthesis, Structure and Electrochemistry of Tetrathiafulvalene Vinylogues Bearing Thienyl and Pyridyl Groups^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1449.
[8]	WANG Fengyan, YAN Ni, WEI Junji, XIA Huiyun, SONG Lifang, SONG Jiale, GAO Lining, YAN Luke. Synthesis, Characterization and Cell Imaging of Water Soluble Polythiophene Derivative^† [J]. Chem. J. Chinese Universities, 2018, 39(11): 2594.
[9]	ZHANG Sihang, HE Yongfeng, FU Runfang, JIANG Jie, LI Qingbi, GU Yingchun, CHEN Sheng. Preparation and Electrochromic Properties of Nano Cellulose/Poly(3,4-ethylenedioxythiophene) Composite Films^† [J]. Chem. J. Chinese Universities, 2017, 38(6): 1090.
[10]	LV Yaokang, LIU Youyou, PAN Yun, LIU Gang, CHEN Jun, GUO Yun, CHU Wenjing, SHEN Lian, ZHANG Cheng. Preparation, Characterisation and Electrochromic Properties of Copolymer Films Based on 3,4-Ethylenedioxythiophene and Pyrrole-3-Carboxylic Acid [J]. Chem. J. Chinese Universities, 2017, 38(3): 484.
[11]	FAN Jianxun, JI Lifei, REN Aimin. Theoretical Study on Charge Transport Properties of Copolymers of Diketopyrrolopyrrole and Oligo-thiophene^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 2053.
[12]	LI Lin, LI Miao, CHAI Baoshan, YANG Jichun, SONG Yuquan, LIU Changling. Design, Synthesis and Biological Activity of Novel Substituted Diamides Derivatives Containing Thiophene Ring [J]. Chem. J. Chinese Universities, 2016, 37(9): 1649.
[13]	SONG Hua,YU Qi,XU Xiaowei,SONG Hualin,JIANG Nan,LI Feng,CHEN Yanguang. Effect of Yttrium and Citric Acid on the Hydrodesulfurization Performance of Unsupported Nickel Phosphide^† [J]. Chem. J. Chinese Universities, 2016, 37(8): 1528.
[14]	LIANG Ansheng, LI Junjie, PAN Chengjun, WANG Lei. Preparation and Thermoelectric Properties of Composites Based on Polythiophene Derivatives with Donor-acceptor Structure^† [J]. Chem. J. Chinese Universities, 2016, 37(6): 1161.
[15]	ZHANG Yan, ZHENG Jing, WANG Juan, GUO Mandong. Preparation and Properties of Doxorubicin Hydrochloride Sensor Based on Molecularly Imprinted Polymer^† [J]. Chem. J. Chinese Universities, 2016, 37(5): 860.