Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (1): 127.

• Articles • Previous Articles     Next Articles

Quantum Chemical Study on The Thermolyses of o-Aminobenzoyl Azide and Its Derivatives

XU Wen-Yuan, HONG San-Guo, TANG Zhi-Gang, LI Yong-Hong   

  1. Department of Chemistry, Jiangxi Normal University, Nanchang 330027, China
  • Received:1998-08-03 Online:2000-01-24 Published:2000-01-24

Abstract: UHF/AM1 method has been applied to study the thermolyses of o-aminobenzoyl, o-amino-p-methylbenzoyl, o-amino-p-formalbenzoyl azides. The results obtained show that these reactions proced through various competing routes yielding to different products, and the activation energy of the rate-determining steps of routes (2)—(4) are lower than that of route(1).

Key words: AM1 method, o-Aminobenzoyl azide, Thermolysis

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