CJCU

Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (S1): 580.

• Teaching and Education in Analytical Chemistry;NMR;Others • Previous Articles     Next Articles

51V NMR for Monitoring[VS4-Cu2] Cluster Synthesis:Transient Kinetic Studies and Evaluation of a Putative Reaction Intermediate

YE Jian-Liang1, CHEN Zhong1, ZHENG Fa-Kun2, CHEN Zhi-Wei1, ZHOU Xing-Wang1, HUANG Jin-Shun2   

  1. 1. Department of Chemistry and the Key Laboratory of Analytical Sciences of MOE, Xiamen University, Xiamen 361005, P. R. China;
    2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science State Key Laboratory of Structure Chemistry, Fuzhou 35002, P. R. China
  • Online:1999-12-31 Published:1999-12-31
  • Supported by:

    Supported by NNSF of China (No. 19605004), State Key Laboratory of Structural Chemistry and the Key Lab. of Analytical Sciences of DOEC

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Abstract:

[VS4-Cun] (n=l,2) cluster hasn't been synthesized due to the strong affinity between[VS4] and Cu. Therefore, synthesis of these complexes require new applications of nondestructive analytical tools to monitor the progress of reactions. Herein we describe 5lV NMR technique to validate the synthesis for[VS4-Cu2] cluster.

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