Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (S1): 203.
• Chromatography and Separation Sciences • Previous Articles Next Articles
Takashi Ito, Kiyotaka Nakaya, Natsumi Ugawa, Yuko Hasegawa
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Abstract:
A remarkable enhancement of the extraction of lanthanoids(Ⅲ)(Ln) with β-diketones in the presence of a Lewis base, so-called synergistic effects, would be caused by the adduct formation of the β-diketonates with the Lewis base. The trend of the variation of the adduct formation constants across the lanthanoid series may be different among β-diketones used. It has also been observed that the trend across lanthanoid series and also the values of the enthalpy change in the adduct formation of the 2-thenoyltrifluoroacetonates(TTA) with 1,10-phenanthroline(phen) are very similar to those with 2,25-bipyridyl(bpy), although the values of the adduct formation constants with the former are larger than those with the latter.
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Takashi Ito, Kiyotaka Nakaya, Natsumi Ugawa, Yuko Hasegawa. Thermodynamic and Spectroscopic Study of the Adduct Formation of Tris(β-diketonato)lanthanoids with Heteroamines[J]. Chem. J. Chinese Universities, 1999, 20(S1): 203.
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http://www.cjcu.jlu.edu.cn/EN/Y1999/V20/IS1/203