Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (11): 1720.
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TANG Liang-Fu, WANG Zhi-Hong, JIA Wen-Li, XU Yu-Ming, WANG Ji-Tao
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Abstract: Mo_Ge bimetallic complexes containing poly(pyrazol-1-yl)alkanes have been synthesized by means of the replacement of CH3CN ligand in (CH3CN)2Mo(Cl)(CO)3·(GeCl3) by poly(pyrazol-1-yl)alkanes. Due to the weaker donating ability, the replacement of bis(3,5-dimethyl-4-halopyrazol-1-yl)methane with (CH3CN)2Mo(Cl)(CO)3(GeCl3) requires heating to start the reaction. All new compounds were characterized by 1HNMR, IR, mass spectra and elemental analyses.
Key words: Poly(pyrazol-1-yl)alkanes, Carbonyl molybdenum, Germanium(Ⅳ) chloride, Bimetallic complexes
CLC Number:
O641
TrendMD:
TANG Liang-Fu, WANG Zhi-Hong, JIA Wen-Li, XU Yu-Ming, WANG Ji-Tao . Studies on the Substitution Reactions of (CH3CN)2Mo(Cl)(CO)3(GeCl3) with Poly(pyrazol-1-yl)alkanes[J]. Chem. J. Chinese Universities, 1999, 20(11): 1720.
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