Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (S1): 338.

• Organometallic Chemistry • Previous Articles     Next Articles

Synthesis and Structure of the first cationic ferrocene C60 derivative

Ying-Huai Zhu, Li-Cheng Song   

  1. Department of Chemistry, Nankai University, Tianjin 300071, China
  • Online:1998-12-31 Published:1998-12-31
  • Contact: 宋礼成,教授

Abstract: The first cationic ferrocene C60 derivative[CpFe(CO)2]4+C60[BF4]4- was synthesized by a new route involving substitution of the loose ligand C3H6 by C60 and characterized by EA, 1HNMR, FAB-MS, IR and UV-vis spectrum. The new air-sensitive compound has a D2h symmetry.

Key words: Fullerenc [C60], Cationic ferrocene (Ⅰ) complex compound, Ligand Substitution

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