Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (S1): 330.
• Organometallic Chemistry • Previous Articles Next Articles
CHEN Xin-Bin, GUI Ming-De, ZHU Shen-Jie
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Abstract: There are many dimetalloenzymes in nature[1]. To mimic these enzymes, we synthesized a new dimanganese Schiff base complex-Bis[N,N'-ethylene-2,2,-(phenylmethylene)-bis(3,4-dimethylpyrrole-5-aldimino)] dimanganese Mn2L (shown in Fig.1). Its structure was confirmed by IR, UV-Vis, 1HNMR and elemental analysis. It can catalyze monooxygenation of cyclohexane with PhIO as an oxidant.
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CHEN Xin-Bin, GUI Ming-De, ZHU Shen-Jie. Effect of Axial Ligands on Monooxygenation of Cyclohexane Catalyzed by A Dimanganese Schiff Base Complex[J]. Chem. J. Chinese Universities, 1998, 19(S1): 330.
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