Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (S1): 196.
• Organic Synthesis Chemistry • Previous Articles Next Articles
Liao Xiangjun, Huang Guiqin, Zhang Chunxiang, Wang Likun, Liu Zhun
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Abstract: Cantharidinum is not only considered the active principle of antineoplastic drug in Chinese traditional medicine[1], but also it and its natrii-cantharidas can be used herbicide and defoliant for legume plants. Seen from the structure of nor-cantharidinamine, it is a five-membered ring glutarimide,which is an active group in pesticide.In 1986,Lacova,M. Reported that the cyclic N-(aryloxyacetyl)-O-dicarboximides exhibited herbicide and fungicide activity[2],but as now there is no report that reports the synthesis and pesticide activity of the cyclic N-(2,4-dichlorophenoxyacetyl)-O-dicarboximides[2].So we base on the derivative of nor-dehydrocantharidin and 2,4-dichlorophenoxyactic acid to make 6 compounds be synthesized,which were characterized elemental analysis, HNMR,MS.Pesticide activities of these compounds are being tested.
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Liao Xiangjun, Huang Guiqin, Zhang Chunxiang, Wang Likun, Liu Zhun. SYNTHESIS OF CYCLIC N-(2,4-DICHLOROPHENOXYACETYL)-O-DICARBOXIMIDES[J]. Chem. J. Chinese Universities, 1998, 19(S1): 196.
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http://www.cjcu.jlu.edu.cn/EN/Y1998/V19/IS1/196