Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (S1): 150.
• Organic Synthesis Chemistry • Previous Articles Next Articles
Haifu GUO, Chusheng HUANG, Wenfei TAN, Yulin LI
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Abstract: The phenols containing geranyl units1 are a large group of interesting natural products exhibited many physiological actions as antiflammatory, antibacterial and antioxidative activities2. Two novel acetophenones 1 and 2 were recently isolated from the fruits of Evodia merrillii, a small folk medicinal tree widely distributed in Taiwan3. Their structures were elucidated as 2-(1'-geranyl)-4,6-dihydroxyacetophenone 1 and 2-(1'-geranyloxy)-2,6,α-trihydroxyacetophenone 2 by means of spectroscopic data. So far as we know, the total synthesis of them have not been reported yet. Herein, we wish to report the first total synthesis of 1 and 2,starting from 2,4,6-trihydroxyacetophenone.
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Haifu GUO, Chusheng HUANG, Wenfei TAN, Yulin LI. Regioselective Synthesis of Two Novel 2-geranyloxyacetophenones[J]. Chem. J. Chinese Universities, 1998, 19(S1): 150.
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http://www.cjcu.jlu.edu.cn/EN/Y1998/V19/IS1/150