Abstract: Phase transfer catalysis is one of the most active techniques used in organic synthesis^[1]. The process is versatile, fast, inexpensive, involves smooth work-up, give good yield and needs less drastic condition compared to conventional methods of synthesis. The technique has a very broad scope of application^[2], surprised, few are have been devised for synthesizing alkyl bromides. Alkyl bromides are important materials in organic synthesis and in agricultural chemical purpose, as well as widely used in the oil field gas exploration and water treatment^[3].