Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (9): 1504.

• Articles • Previous Articles     Next Articles

Studies on Complexation Between β-Cyclodextrin and Sodium Dodecyl Sulfate by Microcalorimetry

ZHU Xiao-Feng1, XU Xu1, LIN Bing-Cheng1, G. Wenz2, S. Wehrle2   

  1. 1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023;
    2. Polymer Institute of Karlsruhe University, D 76187 Karlsruhe, Germany
  • Received:1997-06-03 Online:1998-09-24 Published:1998-09-24

Abstract: The interaction between β-cyclodextrin( β-CD) and sodium dodecyl sulfate(SDS) was studied by microcalorimetry, a Host-Guest binding reaction with 1:2 stoichiometry was calculated, the first and second stability constants are 15.50 mol-1 ·Land 7.95 mol-1 ·Lrespectively. According to the experimental results, several related thermodynamic parameters were also obtained and a possible inclusion model was presented as well.

Key words: Microcalorimetry, Inclusion, β-Cyclodextrin, Sodium dodecyl sulfate

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