Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (7): 1074.

• Articles • Previous Articles     Next Articles

Synthesis and Characterization of 1-Acyloxy(acylamino)-2,8,9-trioxa-5-aza-1-stannatricyclo[3,3,3,01.5] Undecanes

LI Jing, TANG Yong-Jun, LIU Hua, DONG Shu-Ping, XIE Qing-Lan   

  1. Institute of Elemento organo Chemistry, National Key Lab. of Elmento Organic Chemistry, Nankai University, Tianjin, 300071
  • Received:1997-04-17 Online:1998-07-24 Published:1998-07-24

Abstract: Fourteen new 1-acyloxy(acylamino)stannatrane were synthesized. The IR, 1H, 13C, 119SnNMR and elemental analysis were determined. The characteristics of NMRspectra in different solvents showed that the dimer present in chloroform(CDCl3) is decomposed into a monomeric species, involving the very nucleophilic dimethylsulfoxide(DMSO) as a ligand.

Key words: Stannatrane, Dimer, Structure characterization, Coordination compound

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